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San Diego, CA (April 1-6, 2001)
Program Meeting Chair: Carrington Smith
Abstract/Preprint Deadline: Nov. 1, 2000
The preliminary (detailed) program is available.
POLY DIVISION OF POLYMER CHEMISTRY Preliminary Program, 221st ACS National Meeting C. Smith, Program Chair SUNDAY MORNING
Section A
Unknown Room
2001 ACS Award in Polymer Chemistry Honoring David A. Tirrell
T. J. Deming, Organizer, Presiding
8:30 1. Synthesis and properties of synthetic block copolypeptides. T. J. Deming
9:05 2. Applications of protein-based materials in biotechnology: From academia to industry. W. A. Petka, J. L. Harden, A. Karger, G. Drouin, G. W. Slater
9:40 3. ProteinChip(r) system: Proteomics platform for rapid biomarker discovery and validation. J. E. Beecher
10:15 4. Thermo-reversible self-assembly of protein-based nanoparticles. V. P. Conticello, T. A. T. Lee, Y. Zhou
10:50 5. Award Address (ACS Award in Polymer Chemistry, sponsored by ExxonMobil Chemical Co). A polymer chemist's view of protein synthesis and design D. A. Tirrell
Section B
Unknown Room
General Papers
Synthesis/Characterization
C. A. Guymon, Organizer, Presiding
8:30 6. Novel blue light emitting polyhydroxy polyparaphenylenes. S. Valiyaveettil, C. Baskar, S. Wenmiao
8:55 7. Synthesis and micellization of diblock, triblock, and star block methacrylate copolymers S. Pascual, A. Pillay Narrainen, D. M. Haddleton
9:20 8. Anionic copolymerization of styrene and 1,3-cyclohexadiene K. Hong, J. W. Mays
9:45 9. New model for the microphase morphology of segmented polyurethanes and polyureas. I. Yilgor, E. Yilgor, S. Unal, U. Makal, M. Gordeslioglu, E. Yurtsever
10:10 10. Circular dichroism and circularly polarized photoluminescence of helical polyfluorenes. H. Tang, M. Fujiki, M. Motonaga, K. Torimitsu
10:35 11. Diffuse wave spectroscopy finds that PEG delays the aging of a foam. A. H. Fawcett, J. O. Uhomoibhi
11:00 12. Investigation of the coordinate forces in adhesion process for polymer and metal. Y. Liu, R. Wang, Z. Gao, L. Chen, L. Zhang
Section C
Unknown Room
Opportunities and Needs in Polymer Science for Measurement Techniques, Standards, and Future Technologies
Neutron Scattering
J. Antonucci and R. K. Eby, Organizer
E. Amis, Organizer, Presiding
8:30 Introductory Remarks, L. E. Smith
8:50 13. Polyolefin blend miscibility. D. J. Lohse
9:20 14. Probing polymer dynamics with ultra-thin membranes by neutron reflectivity. A. R. Esker, H. Grüll, S. K. Satija, C. C. Han
9:50 15. Structure and property characterization of low-k dielectric porous thin films. B. J. Bauer, E. K. Lin, H. Lee, H. Wang, W. Wu
10:20 Intermission.
10:30 16. Small angle neutron scattering measurements of nanoscale lithographic features. W. Wu, E. K. Lin, Q. Lin, M. Angelopoulos
11:00 17. Ion-induced volume transition in synthetic and biopolymer gels. F. Horkay, P. J. Basser, E. Geissler
11:30 18. Characterization of polymer-clay solutions by rheology, flow birefringence and SANS C. C. Han, G. Schmidt, A. I. Nakatani, A. Karim
SUNDAY AFTERNOON
Section A
Unknown Room
2001 Polymer Division Carl S. Marvel Award for Creative Polymer Chemistry Honoring Craig Hawker
J. M. J. Fréchet, Organizer, Presiding
S. R. Turner, Presiding
1:25 Introductory Remarks.
1:30 19. Convergent synthesis of dendrimers from 1989 to the present. J. M. J. Fréchet
2:00 20. Understanding the catalytic systems for atom transfer radical polymerization. K. Matyjaszewski
2:30 21. Catalytic and free-radical methods for the control of branching in macromolecules. R. Waymouth
3:00 22. Supramolecular polymers. E. W. Meijer
3:30 23. Controlling interfacial interactions: Grafting to and grafting from. C. J. Hawker, T. P. Russell
4:00 24. Complex nanostructured materials made possible by living free radical polymerization methodologies. K. L. Wooley
4:30 25. Award Address (Polymer Division Carl S. Marvel Creative Polymer Chemistry Award, sponsored by ). Controlling nanoscopic structures using well-defined dendritic and living free radical polymers C. J. Hawker
Section B
Unknown Room
General Papers
Synthesis
C. A. Guymon, Organizer
D. A. Spivak, Presiding
1:30 26. Synthesis and characterization of asymmetrically substituted head-to-tail aromatic Schiff-base polymers. M. Jeffries-El, K. C. Ambrosio, R. M. Tarkka
1:55 27. Synthesis of potentially more blood compatible nitric oxide releasing acrylic copolymers. P. G. Parzuchowski, M. E. Meyerhoff
2:20 28. Approaches toward amorphous poly-2,7-fluorene networks D. Marsitzky, K. R. Carter
2:45 29. Cyclopolymerization of bis(methacrylates) incorporating binaphthyl moiety. S. Zheng, D. Y. Sogah
3:10 30. Modeling precise methyl branch placement in polyethylene via acyclic diene metathesis: Synthesis and morphological studies. J. A. Smith, G. Lieser, G. Wegner, K. B. Wagener
3:35 31. New monomers from renewable resources. M. Johansson, J. Samuelsson
4:00 32. Factors affecting amine-acrylic Michael Addition as reactive diluents and polymer synthesis. K. A. Shooshtari, M. R. Van De Mark
4:25 33. Preparation of macromonomers by free radical polymerization in the presence of cationic addition-fragmentation agents. P. Murer, V. Desobry, M. Zink
Section C
Unknown Room
Opportunities and Needs in Polymer Science for Measurement Techniques, Standards, and Future Technologies
New Measurement Techniques
J. Antonucci and E. Amis, Organizer
R. K. Eby, Organizer, Presiding
1:30 Introductory Remarks, E.J. Amis
1:45 34. Characterization of symmetric diblock copolymers with high throughput techniques. A. Karim, A. P. Smith, J. F. Douglas, E. Amis
2:15 35. Combinatorial characterization of biodegradable polymers. J. C. Meredith, A. Tona, H. Elgendy, A. Karim, E. Amis
2:45 36. NIR applications for measuring water sorption and vinyl unsaturation in dental dimethacrylate polymers. S. Dickens, J. W. Stansbury, C. J. E. Floyd
3:15 Intermission.
3:25 37. Making MALDI-TOF-MS an absolute method for the determination of the MMD of polymers. C. M. Guttman, W. R. Blair, S. J. Wetzel
3:55 38. Mass spectrometry of spin-on-glass low-k dielectric precursors. W. E. Wallace, C. M. Guttman, J. Antonucci
4:25 39. Measuring in situ the adsorption of block copolymer amphiphiles and polyelectrolytes at interfaces: A comparison of evanescent, ellipsometric, and acoustic techniques R. C. Advincula, J. W. Mays, W. Knoll, Y. Wang, J. H. Youk, A. Baba, F. Kaneko, M. Park, J. Yang
SUNDAY EVENING
Section A
Unknown Room
General Papers
Synthesis
C. A. Guymon, Organizer
5:30 - 7:30
40. Convenient synthesis of aliphatic polyester catalyzed by distannoxane. M. Ishii, M. Okazaki, Y. Shibasaki, H. Takahashi, T. Hayakawa, M. Ueda
41. Anionic synthesis of polymers of 9,9-dimethyl-2-vinyl-fluorene, 9-methyl-9-trimethylsilyl-2-vinylfluorene and 9-methyl-2-vinylfluorene X. Zhang, T. Hogen-Esch
42. Aqueous ethylene polymerization: Stability of cationic Pd(II) complexes and polymer properties. A. Held, F. Weiss, S. Mecking
43. Controlled radical polymerization of electroluminescent vinyl derivatives. K. R. Carter, D. Marsitzky, P. Blainey
44. Copolymerization of 4-methyl-1-pentene and ethylene with new monocyclopentadienylamido titanium complexes. G. Xu, D. Cheng, Z. Lu
45. Copolymerization of disubstituted polar functionalized 1,3-butadienes M. K. Rath, V. V. Sheares
46. Copolymerization of ethylene with styrene using different constrained geometry catalysts. G. Xu, D. Cheng
47. Cyclopolymerization of templated-bis(methacrylates) derived from asymmetric Diels-Alder reactions. S. Zheng, D. Y. Sogah
48. Development of shielding materials for human space exploration. R. L. Kiefer, J. A. Weakley, D. R. McGlothlin, J. L. Dueber, S. A. Thibeault
49. Effect of particle size on ATRP from the surface of initiator coated silica nanoparticles. T. von Werne, T. E. Patten
50. Effect of zirconium alkoxide on formation of monolithic silica gel via bulk sol-gel process. - Abstract Text not Available Y. Zhang, N. Guo, C. Wang, Y. Bai, Y. Wei
51. Li-ion mediated anionic polymerization of 2-vinylnaphthalene in toluene/THF. G. G. Nossarev, T. E. Hogen-Esch
52. Methods for the preparation of sPS grafited copolymers. S. Chan, C. Li, C. Ting, G. J. Jiang
53. Michael addition of amines to acrylates: Macrocycle formation. K. A. Shooshtari, M. R. Van De Mark
54. Modified bulk sol-gel process. L. Dong, Y. Zhang, L. Fu, C. Wang, Y. Wei
55. New positive-type photosensitive polyimide: Hyperbranched poly(etherimide) with diazonaphthoquinone. M. Okazaki, Y. Shibasaki, M. Ueda
56. New visible light photocatalysts for acrylate polymerization. G. A. Epling, I. A. Banerjee
57. Synthesis and charaterization of novel fluorine-containing polymer with reactive side group. B. Liu, W. Hu, Y. Jin, C. Chen, Z. Jiang, W. Zhang, Z. Wu
58. Novel specialty polymers prepared by well-controlled ring-opening metathesis polymerization. R. A. Charvet, B. M. Novak
59. Ordered 2-D monolayers of nanometer scale rigid cyclic oligomer. T. Ben, C. Chen, H. Cao, X. Liu, H. Qiu, Z. Wu, W. Zhang, H. Ma
60. Synthesis of well defined methacrylate block copolymers by living radical polymerisation. A. Pillay Narrainen, S. Pascual, D. M. Haddleton
61. Polyacetylene containing benzyl carbazole chromophores: Synthesis and photoluminescence. P. P. S. Lee, Y. P. Dong, K. K. L. Cheuk, F. S. W. Chau, B. Z. Tang
62. Polymerization behaviors of poly(ether ketone) via Friedel-Crafts acylation. Y. Sakaguchi, K. Kimura, M. Omori, Y. Yamashita
63. Polymerization studies of thieno[3,4-b]pyrazines D. D. Kenning, M. R. Funfar, S. C. Rasmussen
64. Preparation of photoluminescent oligocarbosilanes by hydrosilylation. C. L. Kepler, S. E. Gradwell
65. Regio- and stereoselectivity for polymerization of diepisulfides catalysed by zinc complexes. T. Satoh, T. Imai, T. Kakuchi, K. Yokota
66. Regioselectivity of enzyme catalyzed transesterification on cellulose. J. Xie, Y. Hsieh
67. Amphiphilic polymeric supports via living radical polymerization. N. Ayres, D. M. Haddleton, A. J. Shooter, D. A. Pears
68. Living anionic polymerization of 2-vinylnaphthalene in the presence of potassium ion. G. G. Nossarev, T. E. Hogen-Esch
69. Ring-opening metathesis polymerization of norbornene in supercritical carbon dioxide. X. Hu, M. T. Blanda, S. R. Venumbaka, P. E. Cassidy
70. Cellulose functionalization by glutaraldehyde(GA). Y. Wang, Y. Hsieh
71. Solid supports for catalysis and separation processes in compressed carbon dioxide. S. A. Crétté, J. M. DeSimone, R. G. Carbonell, W. Tumas
72. Chain extension and properties of biodegradable aliphatic polyesters with unsaturated units. J. Yoon, H. Jin, D. Kim, H. Cho, M. Kim
73. Synthesis and characterization of aromatic polyimides with pendant triflouromethylphenyl groups. H. Zhou, K. Xie, S. Zhang, S. Yang
74. Lyotropic liquid crystalline acid doping of polyaniline. S. R. Hammond, W. Zhou, J. K. Avlyanov, D. L. Gin
75. Synthesis and characterization of controllable crosslinking poly (ether ether ketone). X. Liu, T. Ben, H. Qiu, Z. Gao, H. Cao, C. Chen, Z. Wu, W. Zhang
76. Multifunctional antibacterial cellulose. X. Xu, G. Sun
77. Polylactide-b-polyisoprene-b-polylactide triblock copolymers: New thermoplastic elastomers containing biodegradable segments. E. M. Frick, M. A. Hillmyer
78. Synthesis and characterization of polydiphenylamaleimide. N. C. Yang, J. K. Jeong, D. H. Suh
79. Polymerization of the regular hexagonal phase of tetradecyltrimethylphosphonium methacrylate. D. Y. Markevitch, B. A. Pindzola, D. L. Gin
80. Synthesis and characterization of tanninsulfonic acid-doped polyaniline. J. P. Smith, B. C. Berry, T. Viswanathan
81. Synthesis and chiroptical properties of poly(phenylacetylenes) bearing proline moieties. J. Luo, K. K. L. Cheuk, J. W. Y. Lam, B. Z. Tang
82. Synthesis and cytotoxicity of a D-galactose-containing polyphenylacetylene. B. S. Li, K. K. L. Cheuk, J. Zhou, Y. Xie, J. A. K. Cha, X. Xiao, B. Z. Tang
83. Synthesis and induced helical chirality of poly(phenylacetylenes) with monosaccharide pendants. K. K. L. Cheuk, J. Luo, J. W. Y. Lam, B. S. Li, B. Z. Tang
84. Synthesis and helical conformation of disubstituted polyacetylenes: Polybutynoate and polyphenylpropiolate bearing (-)-menthol pendants. Y. P. Dong, J. W. Y. Lam, K. K. L. Cheuk, J. Luo, B. Z. Tang
85. Synthesis of a well-defined amphiphilic block copolymer via atom transfer radical polymerization. S. Gravano, M. Borden, A. Chen, E. M. Doerffler, T. E. Patten, M. L. Longo
86. Synthesis of poly(2-hydroxyethyl methacrylate)-block-poly(lactide) on gold by dual living polymerization. J. Kim, C. Wang, M. L. Bruening, G. L. Baker
87. Synthesis of novel hydrophilic copolymers containing L,L-lactide and 5-methyl-5-benzyloxycarbonyl-1,3-dioxan-2-one R. F. Storey, B. D. Mullen, K. M. Melchert
88. Synthesis and optical limiting properties of hyperbranched polyphenylenes. K. Xu, H. Peng, B. Z. Tang
89. Synthesis of poly(lactide)/(methyl methacrylate) block copolymers by a combination of ring-opening and atom transfer radical polymerization. T. Liu, G. L. Baker
90. Temperature and pH sensitive IPN hydrogels. H. Chen, Y. Hsieh
91. Synthesis and photoluminescence of hyperbranched polyphenylenes. H. Peng, K. Xu, J. Luo, B. Z. Tang
92. Poly(N,N-dimethylacrylamide) containing pendent perfluorooctyl groups: Reversible hydrogel formation with b-cyclodextrin and sodium 1-adamantanecarboxylate S. J. Tomczak, T. E. Hogen-Esch
93. Temperature-sensitive N-isopropylacrylamide copolymers with hydrophobic spacers. A. Licea-Claverie, R. Salgado-Rodriguez, K. Arndt
94. Synthesis and polymerization of new self-polymerizable quinoxaline monomers. J. Baek, D. J. Klein, F. W. Harris
95. Synthesis and properties of stretchable polyetherimides for alignment layers in liquid crystal displays. H. Wang, S. Z. D. Cheng, F. W. Harris
96. Synthesis and properties of thermally stable and light emitting liquid crystalline poly(butynoate) and poly(phenylpropiolate). J. W. Y. Lam, Y. Dong, B. Z. Tang
97. Synthesis and thermal stability of naphthalene-containing polybutynoate and polyphenylpropiolates. Y. P. Dong, J. W. Y. Lam, B. Z. Tang
98. Synthesis and thermotropic liquid crystalline properties of poly(aryl ether ketone copolymers containing a TERT-butyl side group). H. Sun, H. Wang, C. Chen, Z. Jiang, W. Zhang, Z. Wu
99. Evidence for styrenic structures in polystyrene dimers formed with dibromomethane. E. S. Tillman, T. E. Hogen-Esch
100. Synthesis of electroluminescent organic/inorganic polymer nanocomposites. S. C. Farmer, T. E. Patten
101. Formation of a pure tail to tail dimer of 4-(N,N-dimethylamino)styrene. Block copolymers with styrene W. N. Warner, T. E. Hogen-Esch
102. Synthesis of highly branched polymers having double chains in each monomer unit by grafting-onto method of using living anionic polymers. S. Ryu, A. Hirao
103. Formation of cyclic polystyrene by anionic polymerization: Fluorescence studies. K. A. Alberty, E. S. Tillman, S. Carlotti, S. E. Bradforth, T. E. Hogen-Esch
104. Synthesis of homopolymer and diblock copolymer brushes on silicate substrates by reversible addition fragmentation chain transfer technique. M. Baum, W. J. Brittain
105. Synthesis of N-(2,6-diisopropylphenyl)-3-(bis-2-pyridylmethyl)amino propanamide-Cu(I) complexes for use in atom transfer radical polymerization C. Troeltzsch, M. M. Olmstead, T. E. Patten
106. Synthesis and characterization of macrocyclic poly(2-vinylnaphthalene). G. G. Nossarev, T. E. Hogen-Esch
107. Synthesis of polyarylenevinylene and polyarylenevinylenearyleneethynylene derivatives having a maleimide group. D. H. Suh, N. C. Yang
108. Synthesis of polypropylene-g-polystyrene using the nitroxide mediated radical polymerization. E. Park, J. Yoon
109. Synthesis of soluble poly(ether imide)s derived from various new bis(ether anhydride)s. D. Liaw, C. Hsu, I. Chen, B. Liaw
110. Synthesis, characterization, and antibacterial activity of novel N-halamine polymers Y. Sun, G. Sun
111. Synthesis, stability, and photoluminescence of poly[w-(1-naphthyloxy)-1-alkynes] P. P. S. Lee, K. K. L. Cheuk, Y. P. Dong, F. S. W. Chau, B. Z. Tang
112. Thiophene-based branched conjugated polymers. B. Sankaran, R. A. Vaia, L. Tan
113. Transcarbamation between thermoplastic polyurethane and poly(ethylene-co-vinyl alcohol) during blend processing. D. D. Jiang, R. F. Storey
114. Whisker of Poly(p-oxybenzoyl-alt-Mercaptobenzoyl). K. Kimura, Y. Yamashita, K. Kobashi, Y. Sakaguchi
Section B
Unknown Room
General Papers
Characterization
C. A. Guymon, Organizer
5:30 - 7:30
115. Blends of bitumen with polymers, XII: Design engineering of bulk properties A. H. Fawcett, T. McNally
116. Applications of atomic force microscopy to current problems in industrial polyester chemistry. D. A. Schiraldi, M. L. Occelli, S. A. C. Gould
117. Thermal behavior of poly(lactic acid) related to the application of disperse dyes. I. I. Negulescu, N. E. Lowe
118. Cluster glass transitions in styrene-co-citraconate ionomers. J. Kim, J. Kim, M. Hong, S. Kim, J. Yoo, Y. Lee
119. Contact angle study of PSII treated styrene ionomers: A preliminary study. J. Kim, M. Hong, J. Yoo, J. Yu, Y. Lee, H. Lim
120. Determination of the deactivation rate constants of 1-phenylethyl radical with Cu(II)X2/4,4'-di(5-nonyl)-2,2'-bipyridine H. Paik, K. Matyjaszewski
121. Dynamic mechanical properties and morphology of poly(ethyl acrylate) ionomers containing itaconate ionic groups. J. Kim, S. Kim, J. Yu, S. Jarng, Y. Lee
122. Dynamics of a copolymer chain under an alternating electric field. R. Wenczel, C. Shew
123. Inorganic constitution of silk fibroin. T. Tanaka, J. Magoshi, Y. Magoshi, S. Inoue, M. Kobayashi, H. Tsuda, S. Nakamura
124. Mechanical properties of styrene ionomer blended with diacid molecules. J. Kim, J. Kim, S. Jarng, Y. Lee, W. Kim
125. Monte Carlo simulations for drug carrying capacity of micelles. Y. Chen, C. Shew
126. Morphology of styrene ionomers containing p-aminobenzoic acid. J. Kim, M. Hong, J. Yu
127. Preoaration and some mechanical properties of microcellular polysulfone foam. H. Sun, J. E. Mark
128. Preparation and characterization of organo-silicon dipping film on the surface of optical resins. Y. Wang, R. Pan, B. Wang, B. Yang
129. Preparation and properties of nanocomposites based on polysulfone and an organoclay. H. Sun, G. S. Sur, G. Beaucage, J. E. Mark
130. Preparation and properties of oligo-phenykene vinylene derivative/silica composite film. J. Tang, D. Yu, Y. Wang, C. Wang, B. Yang
131. Rheological evidence of isotropization transition of A thermotropic liquid crystalline poly(aryl ether ketone). H. Sun, C. Chen, H. Wang, Z. Jiang, W. Zhang, Z. Wu
132. Rheological properties of biodegradable aliphatic polyester/montmorillonite nanocomposites. S. T. Lim, Y. H. Hyun, H. J. Choi, M. S. Jhon
133. Second glass transition in weakly clustered poly(styrene-co-itaconate) ionomers. J. Kim, M. Hong, J. Yu
134. Sound-damping properties of styrene-methacrylate ionomers: A preliminary study. J. Kim, J. Kim, J. Yoo, J. Lee, K. Lee, S. Jarng
135. Study on optical properties of transparent resin containing lead ion. Q. Lin, B. Yang, Y. Ma, J. Zhou, X. Meng, J. Shen
136. Surface modifications of PEN films and their wettability. A. Cerisier, B. Hu, R. M. Ottenbrite, J. A. Siddiqui
Section C
Unknown Room
Opportunities and Needs in Polymer Science for Measurement Techniques, Standards, and Future Technologies
E. Amis and R. K. Eby, Organizer
J. Antonucci, Organizer, Presiding
5:30 - 7:30
137. In situ adsorption studies of functionalized poly(styrene-b-isoprene) with zwitterionic groups: Correlation with quartz crystal microbalance and surface plasmon spectroscopy. M. Park, J. H. Youk, S. Pispas, N. Hadjichristidis, R. C. Advincula
138. In situ investigation of adsorption properties of block copolymer amphiphiles by surface plasmon spectroscopy. R. C. Advincula, J. Mays, W. Knoll, Y. Wang, J. Yang, H. Chip, S. Seth, M. Park, J. H. Youk
139. Structural hierarchy in polyisoprene/toluene gels. F. Horkay, G. B. McKenna, E. Geissler
MONDAY MORNING
Section A
Unknown Room
Division of Polymer Chemistry 50th Anniversary
Material Science in the 21st Century I
W. J. Brittain and A. English, Organizer
P. A. Pincus, Presiding
7:55 Introductory Remarks.
8:00 140. Soft actuators. P. de Gennes
8:50 141. Single molecule studies of the extension of polymers in shear, elongational, and mixed flows S. Chu
9:40 142. Polymer materials: Making polymers work. P. Smith
10:30 Intermission.
10:40 143. Novel biomedical materials. R. S. Langer
11:30 144. Functional molecules: A lesson from nature. P. Schultz
Section B
Unknown Room
In-situ Spectroscopy in Monomer and Polymer Synthesis
J. Andrews, J. E. Puskas, and R. Storey, Organizer
T. Long, Organizer, Presiding
C. D. Stokes, Presiding
8:25 Introductory Remarks.
8:30 145. Real-time fiber optic mid-IR monitoring of solution and suspension polymerizations. J. E. Puskas, E. Tzaras, G. Marr, A. J. Michel
9:00 146. Effect of tert-butyl 5-norbornene-2-carboxylate on adhesion and 193-nm lithogrpahic properties of maleic anhydride/norbornene alternating copolymers. A. J. Pasquale, H. D. Truong, R. D. Allen, T. E. Long
9:30 147. Kinetic study of ultrafast polymerization reaction by realtime IR spectroscopy. C. Decker, F. Masson, C. Bianchi
10:00 148. In situ analysis of the thermal elimination reaction in the synthesis of poly(p-phenylene vinylene)(PPV) and PPV derivatives. G. A. Arbuckle-Keil, Y. Liszewski, J. Wilking, B. Hsieh
10:30 149. Monitoring vinyl copolymerizations with near-IR spectroscopy. J. W. Stansbury, J. Tanaka
11:00 150. Real-time monitoring of isocyanate chemistry using a fiber-optic FTIR probe. M. A. Thomson, P. J. Melling, A. M. Slepski
Section C
Unknown Room
Opportunities and Needs in Polymer Science for Measurement Techniques, Standards, and Future Technologies
Crystallization, Interfaces, and Aging
R. K. Eby, E. Amis, and J. Antonucci, Organizer
J. D. Hoffman, Presiding
8:30 Introductory Remarks, J.D. Hoffman
8:45 151. Aspects of the diversity of polymer crystallization habits. F. Khoury
9:15 152. Crystal modulus of silk. A. Sinsawat, S. Putthanarat, S. Zarkoob, Y. Magoshi, J. Magoshi, R. Pachter, M. O. Stone, R. K. Eby
9:45 153. Energy release rate for a crack in a tilted block. A. N. Gent, M. Razzaghi-Kashani
10:15 Intermission.
10:25 154. Reactive processing with difunctional oligomers to increase interfacial adhesion in polymer blends. M. D. Dadmun, C. O'Brien, J. K. Rice
10:55 155. Effect of self-assembled monolayer technology on fiber-matrix adhesion. G. A. Holmes, E. Feresenbet, D. Raghavan
11:25 156. Development and use of novel volatile analysis methods to monitor polymer aging. D. M. Chambers, J. M. Bazan, J. I. Ithaca
Section D
Unknown Room
Silicones and Silicone-Modified Materials
Cosponsored with Division of Polymeric Materials: Science and Engineering
8:00 157. Silicones and silicone-modified materials: An overview. S. J. Clarson
8:30 158. New multi-functional fluorosilicones via the cyclopolymerization of trifluorovinyl aromatic ether monomers. D. W. Smith Jr., S. Narayan-Sarathy, J. Ji, R. H. Neilson, R. Traiphol, D. Perahia
9:00 159. Poly(dimethylsiloxanes) modified with inorganic polyhedra. T. S. Haddad, A. Lee, S. H. Phillips
9:30 160. Amphiphilic polyorganosiloxane nanospheres: Encapsulation of hydrophilic dyes. M. Maskos, M. Schmidt, N. Jungmann
10:00 Intermission.
10:20 161. Synthesis and photo-oxidative degradation of 2,6-bis[w-trimethylsiloxypolydimethyldisiloxy-2'-dimethylsilylethyl]acetophenone J. R. Sargent, S. K. Gupta, W. P. Weber
10:50 162. Polyhedral oligomeric silsesquioxane surfactants. B. Viers, A. R. Esker, C. Farmer
11:20 163. Effect of crosslinkers on the mechanical properties of addition cure phenylsilsesquioxanes. Z. Li, F. McGarry, B. Zhu, D. Katsoulis, J. R. Keryk
MONDAY AFTERNOON
Section A
Unknown Room
Division of Polymer Chemistry 50th Anniversary
Material Science in the 21st Century II
W. J. Brittain and A. English, Organizer
B. M. Novak, Presiding
1:30 164. Dendrimers, conducting oligomers, DNA, and nanocrystals as building blocks for nanotechnology J. M. J. Fréchet
2:20 165. Reactions of single-site olefin polymerization catalysts with functionalized olefins. R. F. Jordan
3:10 Intermission.
3:20 166. Moving from structure to function. G. M. Whitesides
4:10 167. Macromolecular structures for molecular electronics. J. R. Heath, J. F. Stoddart, Y. Luo, C. P. Collier
5:00 Concluding Remarks.
Section B
Unknown Room
General Papers
Hydrophilic/Degradable Polymers
C. A. Guymon, Organizer
K. L. Wooley, Presiding
1:30 168. Estimation of polar and dispersive surface energy parameters of polycaprolactone using the imbedded fiber retraction method. G. Biresaw, C. J. Carriere
1:55 169. Polymer distribution patterns in starch/polylactic acid/poly(hydroxy ester ether) blends by phase modulation photoacoustic spectroscopy. X. Cao, S. H. Gordon, J. L. Willett, D. J. Sessa
2:20 170. Silyl ether-coupled poly(caprolactone)s with stepwise hydrolytic degradation profiles. K. L. Wooley, M. Wang, Q. Zhang
2:45 171. Polymerization of lactones and D,L-lactide initated by lanthanum isopropoxide M. Save, A. Soum
3:10 Intermission.
3:25 172. Polyelectrolytic amphiphilic model networks in water: Synthesis and characterization. C. S. Patrickios, M. Vamvakaki
3:50 173. PS-b-PEO/silica films with regular and reverse mesostructures of large characteristic length scales prepared by solvent evaporation-induced self-assembly. K. Yu, C. J. Brinker, A. J. Hurd, A. Eisenberg
4:15 174. Preparing hydrophilic styrenic block copolymers: Coupling polyetherdiamine with carboxylated polystyrene-block-polybutadiene. R. C. Tsiang, C. Chen
Section C
Unknown Room
In-situ Spectroscopy in Monomer and Polymer Synthesis
T. E. Long, J. Andrews, and J. E. Puskas, Organizer
R. Storey, Organizer, Presiding
1:25 Introductory Remarks.
1:30 175. Investigation of high temperature, isobutylene polymerizations utilizing real-time ATR-FTIR spectroscopy C. D. Stokes, R. F. Storey
2:00 176. Real-time FTIR monitoring and modeling of polymerization reactions. J. Erbes, M. Haehnlein, S. Koltzenburg, A. Schramm
2:30 177. Continuous monitoring of emulsion polimerization using spectroscopic techniques. A. M. Cardenas-Valencia, V. Shastry, J. Vara, L. H. Garcia-Rubio
3:00 178. Kinetic and FTIR spectroscopic investigations of the methanol carbonylation over supported rhodium catalysts. J. Bodis, J. Mink
3:30 179. Helical poly (3-methyl-4-vinylpyridine): In situ observation of the formation of secondary helical structures by CD spectroscopy. I. M. Khan, B. Sannigrahi
4:00 180. Rapid curing of poly(3,4-epoxy-1-butene) in the presence of a redox initiator system Y. Yoo, L. K. Johnson, J. R. Lizotte, A. J. Pasquale, T. E. Long
Section D
Unknown Room
Silicones and Silicone-Modified Materials
S. J. Clarson, J. J. Fitzgerald, S. D. Smith, and M. E. Van Dyke, Organizer
M. J. Owen, Organizer, Presiding
1:10 181. Exploiting silicone-protein interactions: Stabilization against protein denaturation at interfaces. M. A. Brook, P. Zelisko, V. Bartzoka
1:40 182. High temperature/high humidity polyimide coatings for aluminosilicate glass surfaces. S. R. Wagner, R. L. De Rosa
2:10 183. Fluoride catalyzed conversion of b-acetoxyethylsilsesquioxane: Chloride-free precursor for silica films. K. A. Ezbiansky, D. H. Berry, R. J. Composto, B. Arkles
2:40 Intermission.
3:00 184. Adhesion of silicone coatings to polypropylene films. L. O'Hare, S. R. Leadley, B. Parbhoo, J. G. Francis
3:30 185. Plasma polymerized barrier layers. E. M. Johnson, S. J. Clarson, H. Jiang, W. Su, J. Grant, T. J. Bunning
4:00 186. Polymerization of silane quaternary ammonium salts on fibers. R. Kotek, S. Mohamed Abo El Ola, C. White, P. Hauser
4:30 187. Polymethylsiloxane modified polythiophene precursor polymers: Polymer networks for ultrathin film electro-optical applications. R. Advincula, C. Xia
TUESDAY MORNING
Section A
Unknown Room
Division of Polymer Chemistry 50th Anniversary
Previous Marvel Creative Polymer Chemistry Award Recipients I
W. Mattice, Organizer
J. M. DeSimone, Presiding
8:25 Introductory Remarks.
8:30 188. Prediction of melt state rheological properties. L. J. Fetters
9:05 189. Bridging between atomistic and coarse-grained models: Application to the mixing of simple polymeric hydrocarbons. W. L. Mattice
9:40 190. Polymer based microphotonics. E. L. Thomas
10:15 191. Some perspectives on generating controlled oriented semicrystalline morphologies and their importance for practical applications. G. L. Wilkes
10:50 192. Advanced drug and cell delivery systems. R. S. Langer
Section B
Unknown Room
In-situ Spectroscopy in Monomer and Polymer Synthesis
T. Long, J. Andrews, and R. Storey, Organizer
J. E. Puskas, Organizer, Presiding
A. J. Pasquale, Presiding
8:25 Introductory Remarks.
8:30 193. Allure of "molecular videos": In situ IR spectroscopy of polymerization processes. T. E. Long, J. R. Lizotte, A. J. Pasquale, D. T. Williamson, Y. Yoo
9:00 194. In situ NMR monitoring of living radical polymerization: Reaction kinetics and catalyst evolution. D. M. Haddleton, S. Perrier, S. A. F. Bon
9:30 195. In situ proton NMR analysis of radical co- and terpolymerization. H. Ito, D. C. Miller, M. H. Sherwood
10:00 196. Real-time melamine formaldehyde reaction monitoring using in situ FTIR spectroscopy. M. A. Pavlosky, R. Ferwerda, M. Scheepers, J. J. Nusselder
10:30 197. Process monitoring of polymer melts by in-line near IR and Raman spectroscopy in extruders. D. Fischer, E. Pigorsch
11:00 198. Application of FT-NIR spectroscopy for monitoring the kinetics of living polymerizations. M. Lanzendörfer, H. Schmalz, V. Abetz, A. H. E. Müller
Section C
Unknown Room
Silicones and Silicone-Modified Materials
S. J. Clarson, J. J. Fitzgerald, M. J. Owen, and S. D. Smith, Organizer
M. E. Van Dyke, Presiding
8:00 199. Diffusion of polydimethylsiloxane mixtures with silicate nanoparticles. T. Cosgrove, C. Roberts, G. V. Gordon, R. G. Schmidt
8:30 200. Modulus reduction mechanism of trimethylsiloxy silicates in polyorganosiloxanes. R. G. Schmidt, L. R. Badour, G. V. Gordon
9:00 201. In situ spectroscopy in the preparation of polyarylenes, perfluorocyclobutyl polymers, and polylactide derivatives D. W. Smith Jr., E. J. Nelson, K. P. U. Perera, N. Abayasinghe
9:30 202. Application of 1H/13C/29Si 3-D NMR for structural assignment of 1-trichlorosilyl-2-methyl-cyclohexane Isomers. H. Yue, J. P. Cannady, B. Nugent, M. Tzou, M. Chai, P. L. Rinaldi
10:00 Intermission.
10:20 203. Prediction of the elastomeric modulus of poly(dimethyl siloxane) networks formed by endlinking. R. F. T. Stepto, J. I. Cail, D. J. R. Taylor
10:50 204. Influence of hydrogen bonding on the properties of silicone copolymers. I. Yilgor, E. Yilgor, S. Unal, U. Makal
11:20 205. Photoexcitation and -emission spectra of phenylsubstituted siloxanes. M. W. Backer, U. C. Pernisz
Section D
Unknown Room
High Resolution NMR Spectroscopy of Polymers
Tutorial
H. N. Cheng, Organizer
A. D. English, Organizer, Presiding
8:30 206. Modern multi-dimensional NMR spectroscopy of biopolymers - new techniques, new labeling, new parameters, new dynamics R. A. Byrd
9:15 207. Multi-dimensional NMR analysis of synthetic polymers. P. L. Rinaldi
10:00 Intermission.
10:15 208. Computer-aided NMR methods for polymer analysis. H. N. Cheng
11:00 209. Small animal magnetic resonance imaging: Methods and applications. J. R. Garbow, J. J. H. Ackerman
TUESDAY AFTERNOON
Section A
Unknown Room
Division of Polymer Chemistry 50th Anniversary
Previous Marvel Creative Polymer Chemistry Award Recipients II
W. Mattice, Organizer
L. J. Fetters, Presiding
1:25 Introductory Remarks.
1:30 210. Progress in the design and synthesis of artificial proteins. D. A. Tirrell
2:05 211. Biological route to novel electronic and photonic materials. S. Tripathy, W. Liu, R. Nagarajan, P. Wu, S. Roy, J. Kumar, F. F. Bruno, L. Samuelson
2:40 212. Making well-defined polymers the other way: Atom transfer radical polymerization. K. Matyjaszewski
3:15 213. Controlled polymerizations using transition metal complexes. B. M. Novak
3:50 214. Carbon dioxide technology platform. J. M. DeSimone
Section B
Unknown Room
High Resolution NMR Spectroscopy of Polymers
Solution NMR of Synthetic Polymers
A. D. English, Organizer
H. N. Cheng, Organizer, Presiding
1:00 215. Chain end characterization of copolymers containing diphenylphosphinyl ends by 31P-NMR spectroscopy. H. J. Harwood, B. R. Barkes, R. Medsker
1:30 216. NMR/isotopic labeling and mechanistic studies of cationic ring-opening copolymerization. N. Yang, P. Dunn, M. Werner, S. P. Fenelli, J. A. Grates
2:00 217. Recent advances in the NMR description of polypropylenes. A. L. Segre, V. Busico
2:30 218. Effect of internal donors in propylene polymerization with the aid of NMR and internet. R. Chûjô, K. Shimozawa, M. Saito
3:00 Intermission.
3:30 219. Triple resonance multidimensional solution NMR of fluoropolymers: Problems, solutions, and results P. L. Rinaldi, O. Assemat, L. Li, V. Dudipala, S. Stakleff
4:00 220. Compositional and configurational assignments of acrylonitrile copolymers by 2-D NMR spectroscopy. A. S. Brar
4:30 221. Solution NMR characterization of polyimides based on 4,4´-diaminotriphenylmethane A. Martinez-Richa, R. Vera-Graziano, D. Likhatchev
Section C
Unknown Room
Silicones and Silicone-Modified Materials
S. J. Clarson, M. J. Owen, S. D. Smith, and M. E. Van Dyke, Organizer
J. J. Fitzgerald, Organizer, Presiding
1:10 222. Dynamics and structure of polydimethylsiloxane emulsions as studied by pulsed field gradient NMR and small-angle neutron scattering. T. Cosgrove, T. Garasanin Bellenger, A. J. Goodwin, A. Kretschmer, L. Marteaux
1:40 223. Poly(amidoamine-organosilicon) (PAMAMOS) dendrimers and their derivatives of higher degree of structural complexity. P. R. Dvornic, M. J. Owen, S. E. Keinath, J. Hu, L. W. Hoffman, P. L. Parham
2:10 224. Dendrimer-based interpenetrating polymer networks. - Abstract Text not Available D. Teyssié, F. Vidal, I. Hémonic, S. Boileau, S. D. Reeves, P. R. Dvornic, M. J. Owen
2:40 225. Neutron scattering studies of linear and cyclic poly(dimethylsiloxanes). A. C. Dagger, V. Arrighi, S. Gagliardi, M. J. Shenton, S. J. Clarson, J. A. Semlyen
3:10 Intermission.
3:30 226. 2D-NMR and LC-NMR characterization of siloxane/styrene block copolymers. A. M. Morgan, S. K. Pollack, K. Beshah
4:00 227. Synthesis of poly(methylmethacrylate-dimethylsiloxane) block copolymers: Thermal and morphology studies. L. Bes, K. Huan, E. Khoshdel, D. M. Haddleton
4:30 228. High resolution pattern replication utilizing siloxane-modified acrylate network stamps. K. R. Carter, M. E. Best, G. M. McClelland, B. D. Terris
Section D
Unknown Room
Durability of Plastics and Rubbers
Tutorial
P. DesLauriers and N. C. Billingham, Organizer
R. Clough, Presiding
12:55 Introductory Remarks.
1:00 229. Oxidative degradation of polymers: An introduction. N. C. Billingham
1:45 230. Macro-and micro-spectrophotometric techniques for assessing material changes in accelerated conditions. J. Lemaire
2:30 231. Polymer photodegradation and stabilization: A tutorial. J. E. Pickett
3:15 232. Design and durability of high performance/high temperature polymers. P. M. Hergenrother
4:00 233. Lifetime predictions for elastomers from accelerated aging experiments. K. T. Gillen, R. L. Clough
4:45 234. Stabilization of polymers: Introduction. H. Zweifel
Combinatorial Approaches To Polymer Design and Modeling
Cosponsored with Biotechnology Secretariat
TUESDAY EVENING
Section A
Unknown Room
Durability of Plastics and Rubbers
R. Clough, P. DesLauriers, and N. C. Billingham, Organizer
6:00 - 8:00
235. Degradation of a foamed poly(dimethylsiloxane). A. N. Chaudhry, N. C. Billingham
236. Degradation of MDI-based poly(ester urethane) initiated by exposure to dilute concentrations of nitrogen dioxide. E. B. Orler, D. A. Wrobleski, D. W. Cooke, B. L. Bennett
237. Diffusion of slip/antiblocking agents in polyolefins: A study by FTIR ATR spectroscopy and stack experiments. N. C. Billingham, C. Kefaleas
238. Effects of peroxide crosslinking on the oxidative stability of PE-LD: A study using chemiluminescence. P. K. Fearon, S. W. Bigger, N. C. Billingham
239. Formation of self generating, inorganic passivation layer on nylon 6 / layered silicate nanocomposite H. Fong, R. A. Vaia, J. H. Sanders, D. M. Lincoln, P. J. John, A. J. Vreugdenhil, J. Bultman, C. A. Cerbus, H. G. Jeon
240. Hydrogen uptake mechanism of silicone rubber-DEB getter mixture. M. Balooch, L. N. Dinh
241. Investigation of aging signatures of silicone polymers for incorporation into predictive models. B. Balazs, R. S. Maxwell, J. D. LeMay
242. Mechanical properties of thermally-aged glove samples. K. V. Wilson Jr., B. L. Smith, J. M. Macdonald, J. M. Castro, W. P. Steckle Jr.
243. Monitoring thermo-oxidative degradation in elastomers by NMR relaxation measurements. R. A. Assink, D. P. Lang, M. Celina, B. Sanderson, K. T. Gillen
244. Oxidative degradation analysis of HTPB/IPDI polyurethane using 17O and 13C NMR. D. J. Harris, R. A. Assink, M. C. Celina
245. Study of the effects of additive interaction in polymer stabilization. E. Földes, J. Lohmeijer
246. Superposition and wear-out approaches applied to polymer lifetime prediction. M. Celina, K. T. Gillen
247. Crystallization behavior as a tool for assessing changes in high phenyl content silica filled PDMS/PDPS copolymer composite foams. R. Maxwell, B. Balazs, S. DeTeresa, R. Cohenour, L. Thompson
Section B
Unknown Room
Silicones and Silicone-Modified Materials
S. J. Clarson, J. J. Fitzgerald, M. J. Owen, S. D. Smith, and M. E. Van Dyke, Organizer
6:00 - 8:00
248. Synthesis and characterization of poly(N,N-dimethyl acrylamide)-l-poly(dimethylsiloxane) amphiphilic conetworks S. Szabó L, B. Ivan
249. Designing new application-specific silicones for GC columns. D. V. Patwardhan, F. L. Dorman, C. M. English
250. Measuring the size and shape of poly(dimethylsiloxanes) by spectroscopy. M. J. Shenton, A. C. Dagger, H. Herman
251. Novel silicone materials with improved thromboresistance via nitric oxide release. H. Zhang, K. Osterholzer, G. M. Annich, S. I. Merz, J. Miskulin, M. E. Meyerhoff
252. Aliphatic poly(silyl ether)s by Ru-catalyzed hydrosilylation copolymerization of aliphatic a,w-diketones with a,w-dihydrido-oligodimethylsiloxanes J. M. Mabry, W. P. Weber
253. Bioadhesion studies on microtextured siloxane elastomers. W. R. Wilkerson, C. A. Seegert, A. W. Feinberg, L. C. Zhao, M. E. Callow, R. Baney, A. B. Brennan
254. Calculation of large ring concentrations in poly(dimethyl siloxane) systems. R. E. Heath, J. A. Semlyen
255. Characterization of chemically and topographically modified siloxane elastomer. A. W. Feinberg, C. Seegert, W. R. Wilkerson, A. Gibson, L. Wilson, R. Baney, A. B. Brennan
256. Dehydrogenative silylation copolymerization: Synthesis of copoly[arylene-1,2-dioxy/oligodimethylsiloxanylene]s by ruthenium-catalyzed reaction of ortho-quinones with a,w-dihydrido-oligodimethylsiloxanes J. M. Mabry, C. J. Teng, W. P. Weber
257. Divergent synthesis of tetra-branched star polysiloxanes by tetrakis(hydroxydimethylsiloxy)silane/phosphazene P4-t-Bu superbase catalyzed proton transfer polymerization of D3. G. Cai, W. P. Weber
258. Effect of thermal ageing on the non-network species in RTV5370 polysiloxane rubbers. M. Patel, A. R. Skinner
259. Hydrosilation polymerizations with diallyl monomer - benzene solution vs. supercritical carbon dioxide R. Welsch, M. T. Blanda, S. R. Venumbaka, P. E. Cassidy, J. W. Fitch III
260. Improving structural control of PMMA-g-PDMS graft copolymers by ATRP. H. Shinoda, K. Matyjaszewski
261. Nanoporous organosilicates for low k dielectric applications. W. Volksen, R. D. Miller, C. J. Hawker, J. L. Hedrick, M. Toney, P. Rice, T. Magbitang, V. Lee, E. Huang, K. Rodbell, K. Lynn, M. P. Petkov, M. Weber
262. New methods of poly(siloxane) synthesis via phosphoronitrile Chloride Lewis acid catalysis. M. Fielden, J. G. Matisons, C. J. Embery, S. R. Clarke, L. G. Britcher
263. Observations on the synthesis of 1,3,5-tris(3-trimethoxysilylpropyl)-isocyanurate P. M. Miranda, A. MacGregor
264. Phase behavior and structural characterization of trisiloxane surfactant - water - silicon oil systems. P. Alexandridis, S. Ahn
265. Poly[1,1-bis(trimethylsiloxy)-3,3,5,5-tetramethyltrisiloxane] G. Cai, W. P. Weber
266. Preparation and properties of polyhedral oligosilsesquioxanes/polymer blends. R. L. Blanski, S. H. Phillips, A. Lee
267. Preparation of poly(dimethylsiloxane)-graph-oligo(oxyperfluoropropylene) via ring-opening polymerization. M. A. Buese, J. F. Gonzalez, C. G. Harbaugh, G. M. Stearman, M. S. Williams
268. Silica surface treatment effects on the dynamics of poly(dimethyl siloxane) by time-of-flight neutron spectroscopy. A. I. Nakatani, K. S. Kwan, R. Ivkov, P. Papanek
269. Siloxane coupling agents. L. Britcher, J. G. Matisons, D. C. Kehoe
270. Sol-gel chemistry of 3-isocyanatopropyltriethoxysilane. D. A. Loy, C. R. Baugher, D. A. Schneider, A. Sanchez, F. Gonzalez
271. Sol-gel chemistry of amino-functionalized organotrialkoxysilanes. D. A. Loy, A. Sanchez
272. Sol-gel chemistry of epoxy-functionalized organotrialkoxysilanes. D. M. Gara, D. A. Loy
273. Sol-gel chemistry of methacryloxy- and styryl-functionalized organotrialkoxysilanes. M. R. Minke, D. A. Loy
274. Structure-property relationships for poly(dimethylsiloxane) networks in situ filled using titanium 2-ethylhexoxide and zirconium n-butoxide. S. Murugesan, J. E. Mark, G. Beaucage
275. Structures of side chain liquid crystalline poly(silylenemethylene)s. S. Park, T. Zhang, L. V. Interrante, B. L. Farmer
276. Study of curing properties of silicone structural sealant. Y. Wang, L. Liu, H. Wang, Q. Wu
277. Study on the synthesis of optically active polysilane dendrimer. H. Oh, M. Omote, K. Suzuki, I. Imae, Y. Kawakami
278. Synthesis and characterization of a new (tetrasilanol)cyclosiloxane. B. M. Moore, T. S. Haddad, S. Phillips
279. Synthesis and properties of isomeric poly(1-hydrido-1-trimethylsiloxytetramethyltrisiloxane) and poly(1-dimethylsiloxypentamethyltrisiloxane), regular polysiloxanes, that contain both Si-H and RSiO3/2(T) units G. Cai, W. P. Weber
280. Synthesis and properties of new ion conducting polymer: Poly(methacryloxypropyl-di(PDMS-b-TGME)). J. Kim, J. Lee
281. Synthesis of copoly(silyl ether/silyl enol ether)s by ruthenium catalyzed hydrosilylation/dehydrogenative silylation of a-diketones with a,w-dihydrido-oligodimethylsiloxanes J. M. Mabry, W. P. Weber
282. Synthesis of irregular linear cross conjugated copoly[2-trimethylsilyl-1,1-vinylene/2,4'- or 2,4-benzophenonylene] S. K. Gupta, W. P. Weber
283. Synthesis of siloxanes and silsesquioxanes for 157 nm lithography. H. V. Tran, R. J. Hung, D. A. Loy, D. R. Wheeler, J. Byers, W. Conley, C. G. Willson
284. Thermally stable siloxane copolymers for gas chromatography. G. M. Day, R. Cervini, G. J. Sharp
Section C
Unknown Room
High Resolution NMR Spectroscopy of Polymers
H. N. Cheng and A. English, Organizer
6:00 - 8:00
285. 1H/13C/29Si Triple resonance 3-D NMR study of poly(dimethylsiloxane) MD3MH. M. Chai, P. L. Rinaldi, S. Hu
286. 2-D NMR of polymers: Comparison of some of the standard pulse sequences. R. A. Newmark, J. L. Battiste, M. N. Koivula
287. Azocellulose: A novel photodynamic polymer characterized by solid state 13C NMR. A. Cholli, S. Yang, M. M. Jacob, J. Kumar, S. K. Tripathy
288. Cationic copolymerization of trioxane with 1,3-dioxepane: An NMR study N. Yang, M. Cui, Y. Zhang, S. P. Fenelli, J. A. Grates
289. Complex polymer mixture analysis by LC(GPC)-NMR. J. Wu, K. Beshah
290. Conformational analysis of alkylated biuret and triuret: Evidence for helicity and helical inversion. L. D. Ptak, J. D. Thoburn, C. G. Wade
291. Dynamics of deuterated molecules chlathrated in crystalline syndiotactic polystyrene. A. Grassi, E. Trezza
292. Effect of internal donors in propylene polymerization analyzed with the internet system. K. Shimozawa, M. Saito, R. Chûjô
293. Estimation of physical properties of archaeological silk with the aids of NMR relaxation time and fluctuation-dissipation theorem. R. Chûjô, K. Fukutani, Y. Magoshi
294. High field 13-C NMR spectra of chloroprene copolymers. A. H. Fawcett, W. Burns, A. B. Foster
295. Multidimensional NMR studies on polyurethane dendritic wedges. M. Chai, P. L. Rinaldi, U. Puapaiboon, R. T. Taylor
296. NMR investigation on peroxidase-catalyzed polymerization of sulfonated phenol. A. L. Cholli, W. Liu, J. Kumar, S. Tripathy, L. Samuelson
297. Oligomers and fractals of polyester networks. A. H. Fawcett, G. Andrews, M. Hania
298. Photostabilization of PET via photo-Fries' rearrangement. M. Lin, C. Lee
299. Solid state NMR studies of high internal phase emulsion polystyrene foams crosslinked with trivinylbenzene and deuterated divinylbenzene. W. P. Steckle Jr., D. A. Langlois, J. H. Small
300. Structure determination of poly(vinyl alcohol) by 2-D NMR spectroscopy. A. S. Brar, R. Kumar, A. Yadav, M. Kaur
301. Water in hydrogels: An NMR study of water/polymer interactions in lightly crosslinked chitosan networks. A. A. De Angelis, A. L. Segre, D. Capitani, V. Crescenzi
Section D
Unknown Room
In-situ Spectroscopy in Monomer and Polymer Synthesis
T. Long, J. Andrews, J. E. Puskas, and R. Storey, Organizer
6:00 - 8:00
302. In situ characterization of Ziegler-Natta polymerization: Laser reflection interferometry, X-ray photoelectron spectroscopy and thermal desorption of probe molecule S. H. Kim, D. Gnani, G. A. Somorjai
303. Investigation of TiCl4 reaction order in quasiliving carbocationic polymerization of isobutylene. R. F. Storey, Q. A. Thomas
304. Observation of hydrophobic interactions in peptide/polymer non-covalent macromolecular complexes by 2D NOESY 1H NMR spectra. I. M. Khan, K. P. Pemawansa
305. Real-time fiber optic mid-IR monitoring of inimer-type living isobutylene polymerizations. C. Paulo, J. E. Puskas
306. Real-time Fiber Optic Mid-IR Monitoring of Sequential Living Isobutylene and Styrene Block Polymerizations. M. Krombholz, J. E. Puskas
307. Study of ring opening metathesis polymerization kinetics for endo and exo norbornene derivative monomer with in situ 1H-NMR technique. Q. Fu, T. A. P. Seery
WEDNESDAY MORNING
Section A
Unknown Room
2001 ACS Award in Applied Polymer Science Honoring Daniel J. Brunelle
W. J. Brittain, Organizer, Presiding
8:30 308. Nanocomposite formation via cyclic oligomers. X. Huang, S. Lewis, W. J. Brittain, R. A. Vaia
8:55 309. Dialogs with Dan: Collaborative polymer research the "GE way". L. J. Mathias
9:20 310. Materials for use in optoelectronic applications. E. P. Boden, K. P. Chan, H. L. Finkbeiner, D. G. Gascoyne, J. L. Gordon, K. R. Stewart, G. A. Wagoner
9:45 311. Photooxidation of poly(2,6-dimethyl-1,4-phenylene oxide) J. E. Pickett
10:10 312. Recent advances in photoinitiated cationic polymerization. J. V. Crivello
10:35 313. Dendrimers containing a poly(arylene ether sulfone) core: Linear polymers and copolymers. A. S. Hay, C. A. Martinez
11:00 314. Award Address (ACS Award in Applied Polymer Science, sponsored by ). Studies in polycarbonate, polyester, and polyetherimide chemistry D. J. Brunelle
Section B
Unknown Room
Silicones and Silicone-Modified Materials
S. J. Clarson, J. J. Fitzgerald, M. J. Owen, and M. E. Van Dyke, Organizer
S. D. Smith, Organizer, Presiding
8:00 315. Synthesis of alternating polysiloxane copolymers by interfacial polymerization. J. G. Matisons, S. R. Clarke, M. J. Owen, D. Graiver
8:30 316. Spectroscopic, thermal, and mechanical properties of silicone-urea copolymers doped with transition metal salts E. Yilgor, M. Gordeslioglu, B. Dizman, I. Yilgor, E. Kaya
9:00 317. Silicone graft copolymers with styrene, methylmethacrylate and chloroprene A. H. Fawcett, A. B. Foster
9:30 318. Block and graft copolymers containing poly(dimethylsiloxane) and poly(4-vinylpyridine) segments by free radical polymerization. Y. Kim, D. Graiver, G. T. Decker, F. J. Hamilton Sr., H. J. Harwood
10:00 Intermission.
10:20 319. Silicone hydrogels based on methacrylate: Capped multi-block polyurethane-polysiloxane prepolymers. Y. Lai, E. T. Quinn, P. L. Valint
10:50 320. Synthesis and characterization of (star polystyrene)-bl-polydimethylsiloxane-bl-(star polystyrene). D. M. Knauss, T. Huang
11:20 321. Synthesis and properties of poly(butylene terephthalate)-poly(dimethylsiloxane) block copolymers. D. A. Schiraldi
Section C
Unknown Room
High Resolution NMR Spectroscopy of Polymers
Solid State NMR of Synthetic Polymers
H. N. Cheng, Organizer
A. English, Organizer, Presiding
8:30 322. Structure and dynamics of polymer/silsesquioxane mixtures and composites: Solution and solid-state NMR studies. P. A. Mirau, S. Yang
9:00 323. Complex solvent self diffusion and morphology in permeable polymers. P. T. Inglefield, A. A. Jones, W. Wen, Y. Wang
9:30 324. Where are the chain ends in semi-crystalline polyethylene? C. Wutz, E. T. Samulski, M. Tanner, M. Brookhart
10:00 Intermission.
10:15 325. NMR studies of encapsulated polymers. A. E. Tonelli, J. Lu, P. A. Mirau
10:45 326. Solid state 2H NMR spectroscopy of nylon 6 and nylon 6/montmorillonite clay nanocomposites. R. D. Davis, L. J. Mathias, W. L. Jarrett Jr.
11:15 327. High temperature solid-state NMR of cross-linked, insoluble, and unswellable polymers K. A. Thakur
Section D
Unknown Room
Durability of Plastics and Rubbers
Analytical techniques for evaluating degradation
R. Clough and P. DesLauriers, Organizer
N. Billingham, Presiding
8:30 328. Application of gel permeation chromatography to the study of polymer degradation. E. Meehan
9:00 329. Investigation of thermal and g-irradiated hydrolysis in polymers using 17O NMR spectroscopy. T. M. Alam
9:30 330. Some novel approaches to the manipulation of data obtained from chemiluminescence and oxidative induction time experiments. S. W. Bigger, P. K. Fearon, D. J. Whiteman, T. L. Phease, N. C. Billingham
10:00 331. Chemiluminescence from oxidized polymers. L. Rychla III, J. Rychly
10:25 332. Electron spin resonance of radiation-induced oxidation in a poly(ester urethane) containing hard and soft segments. M. S. Jahan, M. C. King, J. M. Gray, D. W. Cooke, B. L. Bennett, E. B. Orler, D. A. Wrobleski
10:50 333. Polymer degradation study by factor analysis of GPC/FTIR data. J. R. Schoonover, S. L. Zhang
11:15 334. Thermo-oxidation mechanism of triblock(ethylene oxide-propylene oxide-ethylene oxide) copolymers analyzed by GC-MS and MALDI. S. Karlsson
11:40 335. Degradable polyethylene and test methods. F. Khabbaz, A. Albertsson
WEDNESDAY AFTERNOON
Section A
Unknown Room
General Papers
Characterization
C. A. Guymon, Organizer
E. B. Orler, Presiding
1:30 336. Structure property relations for poly(acrylonitrile-co-methyl acrylate) carbon fiber precursors. V. A. Bhanu, K. B. Wiles, A. K. Banthia, A. Mansuri, M. Sankarapandian, T. E. Glass, P. Rangarajan, D. G. Baird, G. L. Wilkes, J. E. McGrath
1:55 337. Second look at polythieno[3,4-b]pyrazines: Low band-gap semiconductors and potential metal binding polymers D. D. Kenning, K. A. Mitchell, M. R. Funfar, S. C. Rasmussen
2:20 338. Driving helical geometries with light: From smart polymers to photoresponsive chiroptical switches. G. D. Jaycox
2:45 339. Molecular weight determination of a poly(ester urethane). D. A. Wrobleski, E. B. Orler, M. E. Smith
3:10 340. Toward a standard method for calculating the binding parameters of molecularly imprinted polymers. R. J. Umpleby II, K. D. Shimizu
3:35 341. Structure-property relationships of poly(urethane-urea)s with mixed soft segments of ultra-low monol content poly(propylene glycol) and tri(propylene glycol). M. J. O'Sickey, B. D. Lawrey, G. L. Wilkes
4:00 342. Near-IR two-photon induced polymerizations using either benzophenone or thioxanthone-based photoinitiators. L. L. Brott, R. R. Naik, S. M. Kirkpatrick, D. J. Pikas, M. O. Stone
4:25 343. Pressure dependence of the second virial coefficient of polystyrene solutions. C. L. Moses, W. A. Van Hook
Section B
Unknown Room
Silicones and Silicone-Modified Materials
S. J. Clarson, J. J. Fitzgerald, M. J. Owen, and S. D. Smith, Organizer
M. E. Van Dyke, Organizer, Presiding
1:10 344. Organic/inorganic hybrid materials from polysiloxanes using atom transfer radical polymerization. J. Pyun, H. Shinoda, P. J. Miller, Y. Nakagawa, T. Kowalewski, K. Matyjaszewski
1:40 345. Synthesis and studies of polymers having a [Si-C-Si-O]n backbone structure: The poly(Silylenemethylene-co-Siloxanes). L. V. Interrante, J. Li, Q. Shen
2:10 346. Controlled synthesis of all-siloxane architectures by ring-opening polymerization. J. Chojnowski, M. Cypryk, W. Fortuniak, K. Kazmierski, M. Scibiorek, K. Rozga-Wijas
2:40 Intermission.
3:00 347. Microenvironment and structure of micelles formed by a polymeric siloxane surfactant in aqueous solutions. Y. Lin, P. Alexandridis
3:30 348. Cationic poly(dimethylsiloxane) surfactants: Synthesis, characterization, and aggregation behavior in dense carbon dioxide, fluorinated, and silicon-containing solvents S. L. Folk, J. M. DeSimone, E. T. Samulski
4:00 349. Reactivity of bis(dimethylsilyl)benzene in the catalytic cross-dehydrocoupling polymerization and properties of silphenylene-containing polymers. Y. Kawakami, H. Oh, T. Kawakita, J. Moon, I. Imae
4:30 350. Synthesis of functionalized carbosilane polymers using nucleophilic substitution/ADMET polymerization. A. C. Church, J. H. Pawlow, K. B. Wagener
Section C
Unknown Room
High Resolution NMR Spectroscopy of Polymers
NMR of Biopolymers, I
H. N. Cheng and A. English, Organizer
A. S. Serianni, Presiding
1:00 351. Determining global structure of nucleic acids with dipolar couplings. A. Pardi, E. Mollova, S. McCallum, P. Hanson, K. Bondensgaard
1:30 352. Orientational constraints on polypeptide folds: The role of NMR in structural genomics. J. H. Prestegard
2:00 353. NMR Analysis of structural transition occurred in silk fibroins. T. Asakura
2:30 Intermission.
2:45 354. Origins of the flexibility of complex polysaccharides. C. A. Bush, M. Martin-Pastor, C. J. M. Stroop
3:15 355. Studies on the structure of exopolysaccharides produced by lactic acid bacteria. J. F. G. Vliegenthart, E. J. Faber, J. P. Kamerling
3:45 356. Gelling mechanism of glucomannan polysaccharides and their interactions with proteins. I. C. Baianu, E. Ozu
Section D
Unknown Room
Durability of Plastics and Rubbers
Stabilization and lifetime prediction
R. Clough and N. C. Billingham, Organizer
P. DesLauriers, Presiding
1:00 357. New synergists for hindered amine light stabilizers. P. Gijsman
1:30 358. Action modes of unconventional polymer heat stabilizers: A comparison between 3-arylbenzofuranones and phthalides. C. Krohnke, O. Brede, E. Epacher, B. Pukanszky, B. Turcsanyi
2:00 359. Effect of stabilizers on degradation depth profiles and fracture of UV-degraded polypropylene and polycarbonate. J. R. White, T. J. Turton
2:30 360. How do nanocomposites enhance the thermal stability of polymers? C. A. Wilkie, J. Zhu, F. Uhl
2:55 361. Relating heat age tests to in-service automotive performance of polymeric materials. D. R. Bauer
3:25 362. Polyolefin durability estimates by oxidative stability testing. L. Woo, C. L. Sandford, S. Y. Ding
3:50 363. Combined MOMO analysis of the onset of thermal degradation in polymers. E. Chamot
4:15 364. Crosslink density and molecular weight effects on the viscoelastic response of a glassy high-performance polyimide. L. M. Nicholson, K. S. Whitley, T. S. Gates
4:40 365. Prediction for the lifetime of polymer insulation. N. H. Turner, D. G. Kasture, A. M. Bruning, W. L. Linzey
THURSDAY MORNING
Section A
Unknown Room
Silicones and Silicone-Modified Materials
S. J. Clarson, J. J. Fitzgerald, S. D. Smith, and M. E. Van Dyke, Organizer
M. J. Owen, Organizer, Presiding
8:00 366. Silicone biofouling release coatings: Correlation of compositional variables with macrofouling attachment strength. J. Stein, K. Truby, C. D. Wood, D. Wiebe, J. Montemarano, D. Wendt, C. Smith, E. Holm, A. Meyer, G. Swain, D. Lapota, C. Kavanagh, B. Kovach
8:30 367. Multi-arms PDMS functional stars: Synthesis and characterization. N. G. Vasilenko, G. M. Ignat'eva, E. A. Rebrov, V. D. Myakushev, M. Moeller, A. M. Muzafarov
9:00 368. Silicone elastomeric powders. D. T. Liles, Y. Morita, K. Kobayashi
9:30 369. Hyperbranched Poly(alkoxysiloxanes). W. A. Goedel, M. Jaumann, A. Muzafarov, M. Möller
10:00 Intermission.
10:20 370. Dynamic wetting behavior of hydrosilation-cured polydimethylsiloxane coatings. J. Uilk, R. Hayes, R. B. Fox, K. J. Wynne
10:50 371. Adsorption of an amphiphilic siloxane graft copolymer on hydrophobic particles. Y. Lin, T. W. Smith, P. Alexandridis
11:20 372. Synthesis of vinyloxy acetate/siloxane copolymers for use on E glass fibers. R. Ma, C. Le-Huy, L. G. Britcher, J. G. Matisons
Section B
Unknown Room
High Resolution NMR Spectroscopy of Polymers
Polymer Separations and Polymer Dynamics
H. N. Cheng and A. English, Organizer
P. T. Inglefield, Presiding
8:30 373. On-line HPLC-NMR on polymers. W. G. Hiller, H. Pasch
9:00 374. Tacticity distribution analysis of poly(ethyl methacrylate) by on-line LCCAP-NMR. K. Ute, M. Janco, R. Niimi, T. Kitayama, K. Hatada, D. Berek
9:30 375. Copolymer characterization by SEC-NMR and SEC-MALDI. M. S. Montaudo
10:00 Intermission.
10:15 376. Dynamics of polyacrylates in concentrated chloroform solutions. F. D. Blum, R. B. Durairaj
10:45 377. NMR spectroscopic study of ion conducting 15N labeled polyphosphazenes. T. A. Luther, M. K. Harrup, F. F. Stewart
11:15 378. Dynamics and structures of small oligomers of polyisocyanates by NMR. C. Wade, D. J. O'Leary, J. Roth, K. Armstrong, J. D. Thoburn, D. C. Miller, A. Pomerantz
Section C
Unknown Room
Durability of Plastics and Rubbers
Degradation mechanisms
P. DesLauriers and N. C. Billingham, Organizer
R. Clough, Presiding
8:30 379. Modeling, experimental evidence, and practical consequences of the infectious spreading of oxidative degradation in polymers G. George, I. Blakey, B. Goss, M. Grigg
9:00 380. Poly(vinyl chloride) degradation: Recent mechanistic investigations. W. H. Starnes, V. G. Zaikov, L. B. Payne, Y. Li, X. Ge
9:30 381. Kinetic study of polymeric binders in energetic materials. C. A. Wight, J. D. Peterson
10:00 382. Time-resolved singlet oxygen microscopes: monitoring a key degradation intermediate with spatial resolution. P. R. Ogilby, L. K. Andersen, N. Dam, P. K. Frederiksen, M. Joergensen, L. Poulsen
10:25 383. Effects of tin compounds on thermal and thermooxidative degradation of poly(vinyl chloride). B. Iván, R. Haszanova
10:50 384. New views of an old reaction. F. L. Gugumus
11:15 385. The effect of thermal ageing on the non-network apecies in RTV5370 polysiloxane rubbers. M. Patel, A. R. Skinner
11:40 386. Study of thermal oxidation of stabilized PP films during the induction period. L. Audouin, B. Fayolle, J. Verdu
THURSDAY AFTERNOON
Section A
Unknown Room
Silicones and Silicone-Modified Materials
J. J. Fitzgerald, M. J. Owen, S. D. Smith, and M. E. Van Dyke, Organizer
S. J. Clarson, Organizer, Presiding
1:10 387. Investigations of tin catalysts in silicone RTV systems. S. J. Clarson
1:40 388. Mechanism of the Pt(0) catalyzed hydrosilylation reaction. B. E. Eichinger, J. Stein
2:10 389. Silicon biocatalysis. P. W. Whitlock, S. J. Clarson, L. L. Brott, R. R. Naik, M. O. Stone
2:40 Intermission.
3:00 390. Surfactant properties of poly(2-(dimethylamino)ethylmethacrylate-dimethylsiloxane) triblock copolymers synthesized by copper(I) mediated living radical polymerization. D. M. Haddleton, L. Bes, K. Huan, E. Khoshdel
3:30 391. Silicone substituted phthalocyanines for optical limiting applications. E. M. Maya, A. W. Snow, J. S. Shirk, S. R. Flom, R. G. S. Pong, G. L. Roberts
4:00 392. Mechanistic study on diffusion-controlled titanate-catalyzed condensation of alkoxysilanes in a non-polar solvent. X. Zhou, S. Hu, N. E. Shephard, D. Ahn
4:30 393. Synthesis and curing properties of dimethoxysilyl telechelic polyisobutylenes. S. Hadjikyriacou, R. Faust, T. Suzuki
Section B
Unknown Room
High Resolution NMR Spectroscopy of Polymers
NMR of Biopolymers, II
H. N. Cheng and A. English, Organizer
J. F. G. Vliegenthart, Presiding
1:00 394. Glycan profiling of mammalian tissues and cells by homo- and heteronuclear nano-NMR spectroscopy. H. van Halbeek
1:30 395. Analysis of polysaccharides by NMR and separation techniques. T. G. Neiss, H. N. Cheng
2:00 396. Keratan sulfates: Structural investigations using NMR spectroscopy. T. N. Huckerby, G. M. Brown, R. M. Lauder, I. A. Nieduszynski
2:30 Intermission.
2:45 397. NMR J-couplings in saccharides: Combining theory with experiment. A. S. Serianni, I. Carmichael
3:15 398. Synthesis and physical and NMR characteristics of di- and tri-substituted cellulose ethers. N. (. D. Sachinvala, D. L. Winsor, W. P. Niemczura, K. Maskos, T. L. Vigo, N. R. Bertoniere
3:45 399. 2-D NMR Analysis of ethylcellulose. Q. Xu, M. Brickhouse, H. Wang
Section C
Unknown Room
Durability of Plastics and Rubbers
Degradation under specific environmental stresses
R. Clough and P. DesLauriers, Organizer
N. Billingham, Presiding
1:00 400. Mechanisms and kinetics of polyethylene hydroperoxide reactions in the melt. F. L. Gugumus
1:30 401. Use of rheology to detect and examine the degradation of polyethylene during processing. D. C. Rohlfing, P. J. DesLauriers
2:00 402. Degradation of poly (L-lactide). A. C. Albertsson, F. Khabbaz, M. Hakkarainen
2:30 403. Light stability of thermoset acrylate polymers. C. Decker, K. Zahouily, A. Valet
2:55 404. Effects of relative humidity on moisture-enhanced photolysis of acrylic-melamine polymer coatings: A quantitative study. T. Nguyen, J. Martin, E. Byrd, N. Embree
3:20 405. Use of integrating spheres as uniform sources for polymer photodegradation studies. J. W. Chin, J. W. Martin, E. Embree, E. Byrd, J. D. Tate
3:45 406. Effect of environmental variables on the weathering of some engineering theromplastics. J. E. Pickett
4:10 407. Experimental investigation into g radiation effects in filled and unfilled poly(ester) based poly(urethane)s. J. J. Murphy
4:35 408. Thermal aging of a plasticized poly(ester urethane). E. B. Orler, D. A. Wrobleski, D. W. Cooke, B. L. Bennett, M. E. Smith, M. S. Jahan, M. C. King
5:00 409. Microbiological growth testing on silicone rubber materials for outdoor high voltage insulation. S. M. Wallstrom, K. Dowling, S. Karlsson