2002 SPRING NATIONAL ACS MEETING

Orlando, FL (April 7-11, 2002)

Program Meeting Chair: Carrington Smith

Abstract/Preprint Deadline: Nov. 18, 2001

Polymer Diffraction Methods
Ken Gardner, Dupont CR&D, P.O. Box 80356, Experimental Station, Wilmington, DE 19880-0356; (302) 695-2408, FAX (302) 695-8207, kenn.h.gardner@usa.dupont.com ; John Blackwell, Case Western Reserve U., Macromolecular Science Dept., 2100 Adelbert Rd., Cleveland, OH 44106-7202; (216) 368-6370, FAX (216) 368-4202, jxb6@po.cwru.edu
Self-assembled Photonic Bandgap Materials (cosponsored by PMSE and Society of Plastics Engineers)
E. L. Thomas, Department of Materials Science and Engineering, M. I. T., 13-5094, Cambridge, MA 02139; (617) 253-6901; (617) 258-6175 (secretary); FAX (617) 258-6135; elt@mit.edu; Nitash Balsara, Department of Chemical Engineering, University of California, Berkeley, 201 Gillman Hall, Berkeley, CA 94720-1462; (510) 642-8973, nbalsara@cchem.berkeley.edu.
Chemistry and Engineering of Polyolefins (cosponsored by PMSE and Society of Plastics Engineers)
R. Campbell, Jr., Dow Chemical Co., Bldg 1776, D-3, Midland, MI 48674, (989) 636-3764, FAX (989) 638-9350, recjr@dow.com; Jasson Patton, Dow Chemical Co., Bldg 1776, D-3, Midland, MI 48674, (989) 636-1978, FAX (989) 638-9350, jtpatton@dow.com.
Chromogenic Phenomena in Polymers: Tunable Optical Properties
Samson A. Jenekhe, Dept. of Chemical Engineering, University of Washington, Box 351750, Seattle, WA 98195-1750; (206) 543-5525, FAX (206) 685-3451, jenekhe@cheme.washington.edu; Douglas J. Kiserow, Army Research Office, P.O. Box 12211, Research Triangle Park, NC 27709-2211; (919) 549-4213, FAX (919) 549-4310 or 4399, Kiserow@aro.arl.army.mil.
2002 ACS Polymer Division P.J. Flory Award in Polymer Education Honoring Ulrich Suter
Paul Smith, Department of Materials, ETH Zurich, ETH Zentrum, UNO C 15, Universitätstrasse 41, CH-8092 Zurich Switzerland, psmith@ifp.mat.ethz.ch , Phone: +41 1 632 27 05 (Fax +41 1 632 11 78).
2002 ACS Award in Applied Polymer Science Honoring James E. McGrath
Timothy E. Long, Department of Chemistry, Virginia Polytechnic Institute and State University, Blacksburg, VA 24061-0212, telong@vt.edu , Phone: (540)231-2480 (Fax N/A); Lloyd M. Robeson, Corporate Science and Technology Center, Air Products and Chemicals, Inc, 7201 Hamilton Blvd, Allentown, PA 18195-1501, robesolm@apci.com , Phone: 610-481-5026 (Fax 610-481-6517); Donald R. Paul, Chemical Engineering Department, University of Texas, 26th and Speedway, C0400, Austin, TX 78712, drp@che.utexas.edu , Phone: 512-471-5392 (Fax 512-471-0542).
2002 ACS Award in Polymer Chemistry Honoring Krzysztof Matyjaszewski sponsored by ExxonMobil Chemical Company
Guy C. Berry, Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, PA 15213, gcberry@andrew.cmu.edu, Phone: 412-68-3131 (Fax 412-68-6897); Tomasz Kowalewski, Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, PA 15213, tomek@andrew.cmu.edu, Phone: 412-268-5927 (Fax 412-268-6897).
General Papers

POLY DIVISION PROGRAM

 

This program is NOT final until published by ACS.

Final Program, 223rd ACS National Meeting--Orlando, Florida (April 7-11, 2002)

C. D. Smith, Program Chair

SUNDAY MORNING

Section A

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2002 ACS Award in Polymer Chemistry Honoring Krzysztof Matyjaszewski sponsored by ExxonMobil Chemical Company

I


T. Kowalewski, Organizer
G. C. Berry, Organizer, Presiding

8:30 – 1. Transition metal-catalyzed living radical polymerization: Scope, catalyst design, and precision polymer synthesis M. Sawamoto, M. Kamigaito, T. Ando

9:00 – 2. Self-crosslinkable acetal functionalized latexes and film properties. J. Vairon, F. Mazuel, B. Charleux, C. Bui, K. Loyen, C. Vergé

9:30 – 3. Applications for the CO2 Technology Platform. J. M. DeSimone

10:00 – 4. Using ATRP to Create Morphologically Controlled Conducting Polymer Nanowires. R. D. McCullough

10:30 – 5. Novel Nanostructured Carbon Materials through Self-Assembly in Well-Defined Copolymers. T. Kowalewski

11:00 – 6. Copolymers with various molecular architectures. T. Pakula

11:30 – 7. Template polymerization of monodendritic monomers. M. Möller, X. Zhu, U. Beginn

Section B

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General Papers

Polymer Characterization I


D. Garcia, Organizer
C. S. Patrickios, Presiding

8:00 – 8. The theoretical approach of the relationship between sound absorption coefficient of polymeric materials and its loss factor, and sample thickness J. Wang, X. Yu, Y. Meng, J. Zhang, H. Zhang

8:20 – 9. Topological reorganization of star-shaped polymers. L. Kilian, Z. Wang, A. R. Esker, T. E. Long

8:40 – 10. Toughening styrene maleic anhydride copolymers with SBS and MBS. R. Wang, W. Wang

9:00 – 11. Trapping of the carbon radicals generated by thermolysis of the styrene dimer mimics, 1,2,3,10a- tetrahydrophenanthrene-1,2-dicarboxylic anhydride and 2,3,4,4a-tetrahydrophenanthrene-3,4-dicarboxylic anhydride B. A. Howell, J. J. Powers, P. J. Squattrito, D. B. Priddy

9:20 – 12. Development of renewable resource based bioplastic: Effect of eco-friendly citrate plasticizer on the performance of cellulosic plastic. A. K. Mohanty, L. T. Drzal, A. Wibowo, M. Misra

9:40 – 13. Enthalpic and entropic consequences of photochromic cross-links in thermo-responsive hydrogels of poly(N-isopropylacrylamide). V. K. Gupta, M. Kang

10:00 – 14. Fire-resistant, UV/Visible sensitive polyarylates and copolymers H. Zhang, E. B. Coughlin, P. R. Westmoreland, R. J. Farris, A. Plichta, Z. K. Brzozowski

10:20 – 15. Heteropolyacid/Sulfonated Poly(Arylene Ether Phosphine Oxide) Copolymer Composite Membranes. Y. S. Kim, F. Wang, M. Hickner, J. E. McGrath, T. A. Zawodzinski

10:40 – 16. Nano-engineered model networks: Synthesis, characterization and modeling T. Georgiou, E. Themistou, A. I. Triftaridou, S. C. Hadjiyannakou, M. Vamvakaki, C. S. Patrickios

11:00 – 17. Surface plasmon resonance study of photocrosslinkable hydrogels. M. E. Harmon, D. Kuckling, C. W. Frank

11:20 – 18. Surface vs. bulk competition in various alkane nanoparticles R. Ozisik, W. L. Mattice

11:40 – 19. Functionalized polysiloxanes as fine dispersants for metal particulates. J. K. Hoyt, Y. Kim, J. E. McGrath, J. S. Riffle

Section C

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Self-assembled Photonic Band Gap Materials

Tutorial


N. P. Balsara, Organizer
E. L. Thomas, Organizer, Presiding

9:00 – 20. Interaction between radiation and matter. B. A. Garetz

9:40 – 21. Introduction to the propagation and scattering of light. D. J. Pine

10:20 – 22. Realization of photonic band gap structures. E. L. Thomas

Multi-Layered Polyelectrolyte-Based Materials: Synthesis, Characterization and Applications

Overview and Characterization

Cosponsored with Division of Colloid and Surface Chemistry
See Page X

SUNDAY AFTERNOON

Section A

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2002 ACS Award in Polymer Chemistry Honoring Krzysztof Matyjaszewski sponsored by ExxonMobil Chemical Company

II


G. C. Berry, Organizer
T. Kowalewski, Organizer, Presiding

1:30 – 23. Catalysis in Polymer Science. B. M. Novak

2:00 – 24. A novel approach to 3-dimensional dendritic-like macromolecules. E. M. Harth, B. A. Van Horn, D. S. Germack, C. Gonzales, C. J. Hawker

2:30 – 25. Polymer Synthesis with Transition metal complexes. R. H. Grubbs

3:00 – 26. Functional dendrimers: From synthesis to applications. J. M. J. Frechet

3:30 – 27. Control of macromolecular architecture via expression of artificial genes. D. A. Tirrell

4:00 – 28. The Role of Reversible Deactivation of Growing Species in the Polymerization Processes. S. Penczek

4:30 – 29. Award Address (ACS Award in Polymer Chemistry, sponsored by ExxonMobil Chemical Co). Macromolecular Engineering by Controlled/Living Ionic and Radical Polymerization K. Matyjaszewski

Section B

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General Papers

Polymer Characterization II


D. Garcia, Organizer
G. Biresaw, Presiding

1:30 – 30. Interfacial volume phase transition hysteresis of thermoresponsive core-shell hydrogel nanoparticles. D. Gan, L. A. Lyon

1:50 – 31. Kinetics studies of hybrid structure formation by controlled photopolymerization. Y. Lin, J. W. Stansbury

2:10 – 32. Modeling average properties of star-branched polymers. L. Shiau

2:30 – 33. The effect of ion-incorporation on segmental orientation of polymer chains and guest / host interactions in oriented polymer/dye systems. B. Pan, R. B. Moore

2:50 – 34. The impact of the presence of head-to-head units on the thermal stability of poly(styrene). B. A. Howell, Y. Cui, D. B. Priddy

3:10 – 35. Thermal Decomposition of Styrene Dimer Mimics Derived From Vinylnaphthalenes. B. A. Howell, J. J. Powers, D. B. Priddy

3:30 – 36. Tunable kinetics of core-shell microgel volume phase transitions. L. A. Lyon, D. Gan, C. D. Jones, J. Wang, M. A. El-Sayed

3:50 – 37. Use of SAXS to Characterize the Compatibility of Poly(methyl methacrylate-butyl acrylate)/Polystyrene Soap-free Core-shell LIPN. J. Jin, M. Sun, H. Li, J. Wang

4:10 – 38. Interfacial tension of Eastar Bio Copolyester 14766/polystyrene blends. G. Biresaw, C. J. Carriere

4:30 – 39. Small-angle neutron scattering from strongly charged polyacrylate hydrogels in physiological salt solutions. F. Horkay, P. J. Basser, A. Hecht, E. Geissler

4:50 – 40. Structure and dynamics of liquid silk studied by pulse NMR. M. Kobayashi, T. Tanaka, S. Inoue, H. Tsuda, Y. Magoshi, J. Magoshi

5:10 – 41. Chain Conformation, Dynamics, and Morphology of Adsorbed Random Copolymers V. Nasreddine, L. Reven

Section C

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Self-assembled Photonic Band Gap Materials

I


E. L. Thomas and N. P. Balsara, Organizer
A. J. Ryan and Y. Xia, Presiding

1:00 – 42. Designing composite colloidal particles for photonics. D. J. Pine

1:40 – 43. Irrational self-assembly: 3-D array of holes in a polymer film. M. Srinivasarao, J. O. Park

2:20 – 44. Photonic Bandgap Composites Based On Crystalline Colloidal Arrays. S. H. Foulger, P. Jiang, A. C. Lattam, Y. Ying, D. W. Smith Jr.

2:40 – Intermission.

3:00 – 45. Phase stability in ternary blends for photonics. A. J. Ryan, C. Salou, L. Messe, L. Corvazier, J. P. A. Fairclough, R. N. Young

3:40 – 46. Photonic band gap structures in polymers via self-assembly of block copolymers. S. A. Jenekhe

4:20 – 47. Toward photonic crystals from crosslinked block copolymers. N. P. Balsara, H. Hahn, H. Eitouni

4:40 – 48. Optical properties of block copolymer based metallodielectric photonic crystals. M. R. T. Bockstaller, E. L. Thomas

5:00 – 49. Three dimensionally periodic block copolymer photonic crystals. A. M. Urbas, E. L. Thomas, M. Maldovan, W. C. Carter

Multi-Layered Polyelectrolyte-Based Materials: Synthesis, Characterization and Applications

Colloids

Cosponsored with Division of Colloid and Surface Chemistry
See Page X

SUNDAY EVENING

Section A

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General Papers

Polymer Characterization


D. Garcia, Organizer

6:00 - 8:00

50. Molecular weight distributions in coexisting liquid phases of polystyrene in methylcyclohexane. R. S. Shresth, S. C. Greer

51. Electronic communication between polypyrrole and surface-anchored ferrocene. T. W. Hanks, D. Zhang

52. Polyamide fiber surface induced synthesis of calcium carbonate polymorphs. S. Valiyaveettil, L. Rajamani

53. Crystal structures of new polymeric (4,5-diaza-fluoren-9-one)Cu(I) complexes S. Padhye, P. Kulkarni, C. E. Anson, A. K. Powell, E. Sinn

54. Encapsulation of Fluorescent Dye in Self-assemblies of Carboxylic Diacids on PPI Dendrimer Templates. A. K. Holley, D. He, R. Morgan, M. Chai

55. Impact of the Presence of Acid on the Thermal Decomposition of the Styrene Dimer Mimics, 1,2,3,10a-Tetrahydrophenanthrene-1,2-dicarboxylic Anhydride and 2,3,4,4a-Tetrahydrophenanthrene-3,4-dicarboxylic Anhydride B. A. Howell, J. J. Powers, D. B. Priddy

56. Synthesis and Structure Determination for Styrene Dimer Mimics Derived from Vinylnaphthalenes. B. A. Howell, J. J. Powers, D. B. Priddy

57. Swelling behavior and morphology of interpenetrating polymer network hydrogels based on poly(vinyl alcohol) and poly(acrylamide) used as matrices for cell immobilization. M. E. Calixto, J. Romero, J. E. Angulo-Sanchez, D. Zaragoza, S. Solis

58. 129Xe NMR of Adsorbed Random Copolymers. V. Nasreddine, S. Chijiwa, L. Reven

59. a-Iminoenamido ligands: A Novel structure for transition metal activation. B. Y. Lee, Y. H. KIm, T. H. Kim, G. C. Bazan, D. H. Woodmansee, X. Bu

60. An electroactive indicator. L. Chen, H. Wang, Y. Yu, H. Mao, Z. Wu, W. Zhang, C. Wang, Y. Wei

61. Amorphous poly(ethylene terephthalate): Norbornane comonomers. K. R. Saliba, D. M. Connor, D. A. Schiraldi, D. M. Collard

62. Blue electroluminescence from poly{1-phenyl-1[5-(b-napthoxy)pentyne]s}. Z. L. Xie, J. W. Y. Lam, J. Chen, C. Qiu, M. Wong, H. S. Kwok, B. Z. Tang

63. Charge/distance effect on the glass transition temperatures of poly(ethyl acrylate) ionomers. S. Kim, J. Kim, C. Shin

64. Conductive polymer blend composites for corrosion inhibition. C. Vang, M. Dewald, J. He, A. Richter, D. E. Tallman, G. P. Bierwagen

65. Contact molding for nanoscopic pattern treansfer. K. R. Carter, B. D. Terris, M. E. Best, M. W. Hart, C. T. Rettner, G. M. McClelland

66. Deep curing via near-IR two-photon induced thiol-ene polymerization. K. D. Belfield, K. J. Schafer

67. Different behavior of elution profile of silk fibroin on existence of calcium ion and potassium ion. H. Tsuda, M. Kobayashi, T. Tanaka, S. Inoue, Y. Magoshi, J. Magoshi

68. Effect of inorganic salt on drawing of silk fibroin. T. Tanaka, M. Kobayashi, H. Tsuda, S. Inoue, Y. Magoshi, S. Nakamura, J. Magoshi

69. Effect of polymer-surface mobility on adhesion in poly(methyl acrylate)-tape system. B. C. Gandhi, F. D. Blum, L. R. Dharani

70. Effect of Spacer Length on Blue electroluminescence of Poly (1-Phenyl-1-Alkynes) Bearing Carbazole Moieties. Z. L. Xie, J. W. Y. Lam, J. Chen, Y. Dong, C. F. Qiu, M. Wong, H. S. Kwok, B. Z. Tang

71. Effect of the amount of diacetone acrylamide on the properties of styrene-acrylic copolymer latexes and their films. H. Li, C. Kan, Y. Du, D. Liu

72. Electrorheological behavior of the suspension based on chitosan succinate as the disperse phase. U. S. Choi, Y. G. Ko, Y. S. Park

73. Entrapment and Release Property of Rigid Macrocyclic Oligomer/Keggin Heteropoly Acid System. T. Ben, X. Wang, T. Zhang, H. Cao, Z. Wu, W. Zhang, Y. Wei

74. Formation of colloidal particles of styrene random ionomers studied by a fluorescence technique. J. Kim, J. Kim, H. Oh, J. Yu

75. Glass transitions in miscible ionomer blends of poly(2,6-dimethyl-1,4-phenylene oxide) ionomers mixed with three different styrene ionomers M. Kim, H. S. Jeon, J. Kim, J. Yoo

76. In situ investigations on electrochemical deposition and properties of polyaniline ultrathin films: Electrochemical-surface plasmon resonance spectroscopy using two wavelengths. F. D. Stefani, A. Baba, W. Knoll, C. Xia, R. Advincula

77. Influence of alkali/acid treatment conditions on the generation of nanosize pores inside poly(styrene-ethyl acrylate-acrylic acid) latex particles. C. Kan, P. Zhao, Y. du, D. Liu

78. MALDI -TOF mass spectrometry of acyclic diene metathesis polymers. V. Petkovska, D. Powell, K. Wagener

79. Mechanical properties and morphology of PC/UHMWPE blends with HDPE-g-GMA as a compatibilizer. F. Yang, Y. Zhao, Q. Gao

80. Mechanical Properties and Water Vapor Transport Properties of Sulfonated Block Copolymers. J. M. Sloan, D. M. Crawford, Y. Elabd, E. G. Napadensky, W. Zukas, C. E. Kendrick

81. Mechanical properties of styrene-co-methacrylate and ethyl acrylate-co-acrylate ionomers containing sodium hexanoate. J. Kim, J. Kim, S. Jarng

82. Melt-rheology Properties of Polypropylene/Ethylene-Vinyl Acetate/Zeolite Blend. Y. Yan, Y. Zhao, G. You, J. Chen

83. Method for determination of the elastic modulus of thin polymer gels using the atomic force microscope. E. K. Dimitriadis, F. Horkay, J. Maresca, B. Kachar, R. S. Chadwick

84. Micellization of p-type copolymers in a selective solvent: A Monte Carlo simulation. W. H. Jo, J. Huh, S. H. Kim, K. H. Kim

85. Miscibility of poly(ethyl acrylate-co-acrylate) ionomers with poly(ethyl acrylate-co-itaconate) ionomers. J. Song, H. S. Jeon, J. Kim

86. Monodisperse core-shell molecularly imprinted polymer microspheres. Y. Chen, K. D. Shimizu

87. Monte Carlo simulation of deformation of a poly(vinylidene fluoride) chain under electric fields. Y. Chen, C. Shew, H. Fynewever

88. NMR Study of Self-assembled Inverse Micelles from PPI Dendrimer Templates. D. He, A. K. Holley, M. Chai

89. Novel fluorinated poly(aryl ether)s with low dielectric constants. B. Liu, W. Hu, C. Chen, G. Wang, Z. Jiang, W. Zhang, Z. Wu

90. Novel preparation and characterization of activated carbon fiber. Y. G. Ko, U. S. Choi, J. S. Kim, D. J. Ahn

91. Oxidized Transport Layer: A Stable Semiconducting Polymer with Controlled Conductivity. B. Hsieh

92. Photoprocessibility of photoinduced surface-relief-gratings for polymers containing methyl substituted azo chromophores. Y. He, X. Wang

93. Polystyrene layers grafted from melt to a functionalized silicon surface. K. S. Iyer, V. Klep, I. Luzinov

94. Properties of controllable crosslinking poly(aryl ether ketone)s. X. Liu, C. Chen, H. Cao, T. Ben, W. Zhang

95. Release of Tetracycline Hydrochloride from Electrospun Polymers. E. Kenawy, G. L. Bowlin, K. Mansfield, J. Layman, E. Sanders, D. G. Simpson, G. E. Wnek

96. Self-assembled heterocycle-based films. Evidence of the high donor efficiency of the pyrrol-2-yl group in push-pull chromophores A. Facchetti, A. Abbotto, L. Beverina, M. E. van der Boom, T. J. Marks, G. A. Pagani

97. Self-consistent calculation of geometry and spin density of an iron oxide nanoparticle in acid surfactants. M. B. Pomfret, C. Shew, N. Yang, A. Ulman

98. Shear-induced stabilization of the nematic phase in a side group-containing poly(aryl ether ketone) copolymer. J. Ma, H. Wang, H. Sun, L. Chen, C. Chen, Z. Wu

99. Small-angle X-ray scattering study on poly(ethyl acrylate-co-itaconate) ionomers neutralized with various cations. J. Song, S. Kim, J. Kim

100. Solid-state NMR investigations of Crown Ether/Polystyrene blends. H. W. Beckham, T. Zhao

101. Strcture and characterization of a novel fluorine-containing epoxy resin. C. Zhang, H. Na, J. Cao, J. Mu, C. Liu, Z. Liang, X. Li, S. Liang, Z. Jiang, Z. Wu

102. Study of modified polysulfone/polybenzimidazole composites and their application as microcellular foams. H. Sun, N. Venkatasubramanian, M. D. Houtz, J. E. Mark, F. E. Arnold

103. Study on degradation of PET in supercritical ethylene glycol. H. Wang, L. Chen, X. Liu, Y. Zheng, Z. Wu, Y. Zhou

104. Study on Lung Targeting Erythromycin-poly(DL-lactic acid) Microspheres. Y. Bing, Z. Yao Ming, M. Hang Zhen, W. Zhao Yang, Y. Fan

105. Swelling kinetics of polyacrylate gel beads in physiological salt solutions. F. Horkay, K. Haselkorn, I. Tasaki, P. J. Basser

106. Synthesis and characterization of silk-like polyurethanes with main-chain liquid crystalline soft segments. G. S. Pollock, P. T. Hammond

107. Tetrafluorophenols: New functional structures for 157 nm lithography. Y. Kwark, K. Douki, V. Vohra, X. Liu, W. Conley, P. Zimmermann, C. Ober

108. The influence of surface modification and compatibilization on the performance of natural fiber reinforced biodegradable thermoplastic polyester composite. D. Hokens, A. K. Mohanty, M. Misra, L. T. Drzal

109. Thermogravimetric Studies of PMMA on Silica. B. Zhang, F. D. Blum

110. Toward crown ether containing semifluorinated polyarylene amides for lithium battery membranes. C. M. Topping, J. Jin, S. C. Ligon, A. V. Patil, D. W. Smith Jr., S. Fallis, J. A. Irvin, D. D. DesMarteau

111. Dye sensitized formation of graft copolymers of poly(ethylene glycol) diacrylate-BSA hydrogels in the presence of visible light. I. A. Banerjee, G. A. Epling

Section B

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General Papers

Polymer Synthesis


D. Garcia, Organizer

6:00 - 8:00

112. Synthesis of an amphiphilic styrenic block copolymer. R. C. Tsiang, G. Shen

113. Synthesis and Characterization of Controlled Molecular Weight Poly(arylene ether sulfone) Copolymers Bearing Sulfonate Groups by Endgroup Analysis. F. Wang, T. E. Glass, X. Li, M. Hickner, Y. Kim, J. E. Mcgrath

114. Synthesis and characterization of fluorinated terpolymers. K. D. Belfield, G. G. Abdel-Sadek, J. Huang, R. X. Ting

115. Synthesis and characterization of telechelic and random poly(ethylene terephthalate) ionomers. Q. Lin, N. Gariano, P. H. Madison IV, Z. Wang, V. K. Long, T. E. Long, S. Armentrout

116. Synthesis and properties of arm- or core-functionalized star-shaped polymers. S. Kanaoka, C. Koyama, S. Nakata, H. Yamaoka

117. Synthesis and self-assembly of poly(ferrocenylphenylphosphine) diblock copolymers: Formation of spherical micelles with an organometallic core. L. Cao, M. A. Winnik, I. Manners

118. Synthesis of high molecular weight telechelic poly(1,3-cyclohexadienes) D. T. Williamson, C. L. Hudelson, T. E. Long

119. Synthesis of well-defined chromophore-containing polymers via RAFT polymerization. D. A. Shipp, M. Skasko

120. Copolymers of MMA and Polyhedral Oligosilsequioxanes. J. Xiao, F. J. Feher

121. Design of monomeric and polymeric sulfur based materials. A. S. Abd-El-Aziz, S. L. McFarlane, T. H. Afifi, T. C. Corkery

122. Heterocycles as Protecting Groups: Hydrogenation Routes to Amine Block Copolymers. Y. Aoyama, B. M. Novak

123. Lipase-Catalyzed Chemo- and Diastereo selective Synthesis of Novel Sugar Based Macromer. R. Kumar, R. A. Gross

124. Investigation of chemoselectivity and regioselectivity in anionic ring-opening polymerization of cyclotetrasiloxanes. - Abstract Text not Available C. J. Teng, W. P. Weber

125. Synthesis of hyperbranched poly(ether-ketone) containing quinoxaline moiety from an AB2 monomer in polyphosphoric acid/P2O5. J. Baek, L. Tan

126. Synthesis of liquid-crystalline poly(aryl ether ketone)s. B. Liu, D. Wang, W. Hu, Z. Jiang, W. Zhang, Y. Yang, Z. Wu

127. Synthesis of novel liquid crystalline polymer with perfluorinated alkyl side groups. B. G. Kim, J. Lee, E. Lee

128. Synthesis of novel polymeric/ceramic composites as potential bone substitutes. K. A. Boduch, T. Chapman, K. Marra, S. Petricca, P. Kumta

129. Synthesis of novel thermotropic liquid-crystalline poly(aryl ether ketone)s with (3-methyl)phenyl side groups. B. Liu, D. Wang, W. Hu, Y. Jin, X. Rao, Z. Jiang, W. Zhang, Z. Wu

130. Synthesis of ordered mesoporous material with crystalline microporous framework. Y. K. Kwon, G. Kim, B. D. Choi, D. H. Kim

131. Synthesis of PLLA(I): Direct melt polycondensation of L-lactic acid. M. Hangzhen, Z. Yaoming, W. Zhaoyang, Y. Bing

132. Synthesis of PLLA(II): Post-polycondensation of poly(L-lactic Acid). W. Zhaoyang, Z. Yaoming, M. Hangzhen, W. Jun, Y. Bing

133. Synthesis of poly(2,5,5-trimethyl-2-trimethylsilyloxy-1-oxa-2,5-disila-1,5-pentanylene) by anionic ring opening polymerization (AROP) of 2,5,5-trimethyl-2-trimethylsiloxy-1-oxa-2,5-disilacyclopentane G. Cai, W. P. Weber

134. Synthesis of poly(aryl ether nitrile)s with fluorinated pendant groups. Y. Jin, W. Hu, B. Liu, X. Rao, Z. Jiang, Z. Wu

135. Synthesis of poly(ether-ketones) and a poly(ether-sulfone) using polyphosphoric acid/P2O5 as polymerization medium. J. Baek, L. Tan

136. Synthesis of poly(pentafluorostyrene) via atom transfer radical polymerization. A. M. Granville, W. J. Brittain

137. Synthesis of poly(vinyl alcohol-b-styrene) block copolymer by consecutive telomerization, ATRP, and saponification C. G. Cho, G. H. Li

138. Synthesis of polymeric salen complexes and application in the enantioselective recations as catalysts. G. Kim, Y. K. Kwon, D. Park

139. Synthesis of polyphosphonium salts. H. Ghassemi, J. E. McGrath

140. Synthesis of poly[3-(2-thiophenecarbonyl)-2,5-thiophene] via nickel(0)-catalyzed coupling E. C. Hagberg, V. V. Sheares

141. Synthesis of side-chain polymers with hydrogen bonding recognition sites via ROMP of norbornenes bearing diaminotriazine groups. L. P. Stubbs, J. Adams, M. Weck

142. Synthesis of well-defined (1Æ6)-a-D-glucopyranan by ring-opning polymerization of 1,6-anhydro-2,3,4-tri-O-allyl-b-D-glucopyranose using triflates M. Mori, A. Kusuno, T. Satoh, H. Kaga, M. Miura, K. Tsuda, T. Kakuchi

143. Synthesis, chracterization and properties of tethered ABA type triblock copolymer brushes of styrene and methyl acrylate S. G. Boyes, W. J. Brittain, X. Weng, S. Z. D. Cheng

144. Synthesis, light emission, and optical limiting of hyperbranched polyarylenes H. Peng, L. Cheng, J. Luo, K. Xu, B. Z. Tang

145. The Hydrogel Prepared from Cationic Copolymer - 2. Y. Zhong, J. Jachowicz

146. The preparation and properties of containing an oligo-phenylene vinylene derivative self-assembled multilayer film and sol-gel composite film. J. Tang, L. An, X. Yu, G. Zhang, B. Yang, M. Jiang

147. Trifluoromethylated aromatic poly(ether sulfone)s. W. Hu, B. Liu, J. Zhou, Z. Jiang, W. Zhang, Z. Wu

148. Unsymmetrical poly(silyl ether)s by ruthenium catalyzed polymerization of w-dimethylsilyloxy ketones. J. M. Mabry, W. P. Weber

149. Use of precipitons for copper removal in atom transfer radical polymerization. M. E. Pallack, W. J. Brittain, T. Bosanac, C. S. Wilcox

150. Vacuum deposition of ultrathin polymer films to substrate surfaces: Post-deposition grafting with photoreactive groups. T. Fulghum, A. Prussia, H. Usui, A. Katayama, K. Tanaka, R. Advincula

151. Vinylene-linked donor-acceptor polymers. L. G. Madrigal, J. R. Reynolds, M. Pinto, K. S. Schanze

152. Aqueous atom transfer radical polymerization from gold surfaces. W. Huang, M. L. Bruening, G. L. Baker

153. Characterization of Reversible Polymerization Utilizing DNA Base Pairing. E. A. Fogleman, V. R. Kempf, S. L. Craig

154. Convenient synthesis of hyperbranched polyarylenes by copolycyclotrimerization. L. Cheng, H. Peng, J. Luo, B. Z. Tang

155. Design and synthesis of coordination polymer gels ("metallogels"). B. Xing, M. Choi, Z. Y. Zhou, B. Xu

156. Enantiomer-selective polymerization of (RS)-(phenoxymethyl)thiirane using ZnEt2/L-amino acid. T. Imai, T. Satoh, T. Kakuchi

157. Enantiomer-selective radical cyclopolymerization of rac-2,4-pentanediyl dimethacrylate using chiral bipyridine M. Tsuji, R. Sakai, T. Satoh, H. Kaga, T. Kakuchi

158. Enzymatic Approach for the Synthesis of a Functionalised Amphiphillic Polymer using Candida Antarctica Lipase (CAL). N. A. Shakil, M. Chen, V. S. Parmar, A. C. Watterson, R. Kumar

159. Fabrication of hollow polystyrene nanosphere in microemulsion polymerization using triblock copolymer. J. Jang, H. Ha

160. Fabrication of optically transparent PMMA/silica hybrid using in-situ sol-gel process. J. Jang, J. Ha

161. Graft polymerizations initiated from patterned polymer surfaces. K. R. Carter, T. A. von Werne, C. Hawker, D. Germack

162. Grafting of high-density poly(ethylene glycol) brush to poly(glycidyl methacrylate) monolayers. B. Zdyrko, V. Klep, I. Luzinov

163. Homo- and co-fluorinated acrylic ester polymers: synthesis, characterization, and coating onto silicon surfaces K. D. Belfield, G. G. Abdel-Sadek

164. In situ Generation of Polyaniline in Poly(dimethylsiloxane) Networks. S. Murugesan, G. Sur, G. Beaucage, J. E. Mark

165. Inhibition of enzymatic ring opening polymerization of caprolactone and pentadecalactone by lactide. B. Kalra, M. Kunioka, A. Kumar, R. A. Gross

166. Investigation on effect of cmc0 and cmcw on emulsification process of polymers. H. Wang, D. Liu

167. Kinetics of acyclic diene metathesis with ruthenium olefin metathesis catalysts. S. E. Lehman Jr., K. B. Wagener

168. Lipase-catalyzed synthesis of olefin end-functionalized polyester macromers. B. Kalra, A. Kumar, R. A. Gross

169. Living anionic surface initiated polymerization (LASIP): synthesis and characterization of Block Copolymers. M. Park, G. Sakellariou, S. Pispas, N. Hadjichristides, J. Mays, R. Advincula

170. Metal Catalyzed Bis-Ortho-Diynyl Arene (BODA) Polymerization. P. U. Perera, T. Floyd, D. W. Smith Jr.

171. Methylated and trifluoromethylated aromatic poly(ether ether ketone diphenyl ketone)s. W. Hu, B. Liu, S. Zhao, C. Chen, G. Wang, Z. Wu, Z. Jiang

172. Microemulsion polymerization for hollow polymer nanosphere using encapsulation of a hydrophobe. J. Jang, K. Lee

173. Morphological Control over Recognition-Induced Polymersomes. R. Thibault Jr., M. Gray, T. H. Galow, E. Turnberg, H. Peter, V. M. Rotello

174. New phenylphosphine oxide containing perfluorocyclobutyl (PFCB) polymers for potential space applications. J. Jin, M. S. Kumar, S. H. Foulger, D. W. Smith Jr., H. Liu, B. Mojazza, P. Go, A. Shep

175. Non-Covalent Block Copolymers By Self-Assembly: New Polypseudorotaxanes. Z. Ge, J. W. Jones, H. W. Gibson

176. Novel poly(carbonate) and poly(carbonate-ester) networks. T. F. Al-Azemi, K. S. Bisht

177. Novel Polyester Hydroxy Ether Terpolymers from Lactide and Bisphenol-A Derivatives. N. K. Abayasinghe, D. W. Smith Jr.

178. Novel Synthesis of Crosslinkable Fluorinated Polysiloxanes by Hydrosilation in Toluene and Supercritical Carbon Dioxide. H. Zhou, S. Venumbaka, J. Fitch, P. Cassidy

179. Novel synthesis of ion exchange fiber based on PAN fiber and adsorption study using FT-IR spectroscopy. Y. G. Ko, U. S. Choi, J. S. Kim, Y. J. Chun, D. J. Ahn

180. Novel trimethacrylates: synthesis, characterization and evaluation of new monomers for improved dental restoratives F. Gao, S. R. Schricker, Y. Tong, B. M. Culbertson

181. Organic/inorganic hybrid copolymer for light emitting material. L. You, G. Cai, W. P. Weber, P. lu

182. Polymerization and optical properties of PFCB polymers containing naphthalenes. S. E. Lee, D. S. Lee, C. E. Kim, D. K. Yi, M. Kim, B. Shin, J. Kang, J. Kim, D. Kim

183. Polymerization of 3-methylenehydroxy derivatives of bile acids. F. Zuluaga, M. Larrahondo, K. B. Wagener

184. Polymerization of tricyanoalkenes via sugar reagents. I. Kim, D. J. Sandman

185. Polypyrrole nanoparticles and their supramolecular assemblies prepared using microemulsion polymerization. J. Jang, J. H. Oh, G. D. Stucky

186. Polystyrene latexes with poly(propyleneimine) dendrimers in the core. Z. Xu, W. T. Ford

187. Poly[(2-alkyloxy-5-methyl-1,3-phenylene)-alt-(p-phenylenevinylene)]s with different trans/cis-olefin content: Their synthesis and luminescent properties L. Liao, Y. Pang, L. Ding, F. E. Karasz

188. Preparation and characterization of yellowish polyacrylate latex. J. Wang, C. Kan, D. Liu

189. Preparation of an Amphiphilic ABA Triblock Copolymer Brush for Surface Patterning. W. Huang, G. L. Baker, M. L. Bruening

190. Preparation of aromatic poly(ether nitrile) and poly(ether sulfone) with (3-methyl)phenyl pendant groups. W. Hu, B. Liu, X. Rao, Z. Jiang, W. Zhang, Z. Wu

191. Protected secondary amine organolithium initiators for the living polymerization of hexamethylcyclotrisiloxane (D3). C. L. Hudelson, T. E. Long

192. Radical telomerization of vinylidene fluoride in the presence of dibromodifluoromethane as telogen. K. D. Belfield, G. G. Abdel-Sadek, J. Huang, R. X. Ting

193. Rapid monomer consumption during initiation of quasiliving cationic polymerization of styrene. Q. A. Thomas, M. J. Dillenkoffer, R. F. Storey

194. Ring opening polymerization of lactides using nucleophilic organic catalysts. E. F. Connor, G. Nyce, M. Myres, A. Möck, F. Nederberg, J. L. Hedrick

195. Ruthenium catalyzed chemical modification of poly(vinylmethylsiloxane) with 9-acetylphenanthrene. S. K. Gupta, W. P. Weber

196. Ruthenium-catalyzed hydrosilylation copolymerization of octane-2,7-dione with a,w-dihydrido-oligodimethylsiloxanes M. K. Runyon, J. M. Mabry, W. P. Weber

197. Effect of Critical Overlapping Concentration on the Extent of Chain Transfer to Polymer in the Free-Radical Polymerization on n-butyl Acrylate Monomer. N. M. Ahmad, P. A. Lovell, F. Heatley

198. Synthesis and characterization of elastomeric liquid crystal block copolymers. L. C. McAfee, P. T. Hammond

199. Synthesis and Characterization of New Cross-Linkable Polynorbornene Having Methacryloyl Group Derived from 5-(Methyl methacryloyl)bicyclo[2.2.1]hept-2-ene Using Ring-Opening Metathesis Polymerization (ROMP) D. Liaw, C. Huang, J. Tsai, P. Wu

200. Synthesis and Characterization of new Fluorinated Polyimides. H. Zhou, C. Chen, S. Zhang, S. Yang

201. Synthesis and characterization of rigid-rod Benzobisazole polymers incorporating Naphthalene-2,6 and 1,5-diyl structural units T. D. Dang, N. Venkatasubramanian, A. Talicska, S. Park, F. E. Arnold

202. Synthesis and characterization of silk-like polyurethanes and polyesters using a semi-crystalline soft segment. L. T. James-Korley, P. T. Hammond

203. Synthesis and characterization of star-shaped polystyrene having b-cyclodextrin-core. N. Sugimoto, T. Matsuda, Y. Miura, A. Narumi, T. Kakuchi

204. Synthesis and characterization of sulfonated polyimides based on six-membered ring as proton exchange membrane. Y. Hong, B. Einsla, Y. Kim, J. E. McGrath

205. Synthesis and liquid crystalline behavior of photoreactive side-chain liquid-crystalline polyoxetanes containing cinnamoyl biphenyl mesogen. G. Fan, C. Hsu

206. Synthesis and liquid crystalline properties of poly(oxyethylene)s with azobenzene side groups. T. Kim, J. Lee

207. Synthesis and physical properties of poly(diphenylmethyltrifluoropropylsiloxane)-b-polyimide copolymer as a inter layer dielectric material. D. W. Kang, Y. M. Kim

208. Synthesis and Rheological Study of Polyacrylonitrile Copolymer Carbon Fiber Precursors Using Cost Effective Water Based Synthesis Routes. V. A. bhanu, K. B. Wiles, M. Bortner, D. Godshall, T. E. Glass, D. G. Baird, G. L. Wilkes, J. E. McGrath

209. Synthesis and sol-gel chemistry of bis(diethoxymethylsilylpropyl)urea. D. M. Gara, D. A. Loy

210. Synthesis of 2,2'-methylenebis(1,3-dimethylcyclopentadienyl)zirconium dichloride and its reactivity to the ethylene-norbornene copolymerization B. Y. Lee, Y. H. KIm, Y. C. Won

211. Synthesis of 2,5-dimethyl-2,5-bis(trimethylsilyloxy)-1-oxa-2,5-disilacyclopentane and 2-methyl-2,5,5-tris(trimethylsilyloxy)-1-oxa-2,5-disilacyclopentane V. R. Ziatdinov, G. Cai, W. P. Weber

212. Synthesis of a charged 1,1-diphenylethylene (DPE) derivative and its intercalation into montmorillonite clay for living anionic surface initiated polymerization X. Fan, C. Xia, W. Cristofoli, Q. Zhou, J. Mays, R. Advincula

213. Synthesis of a doubly spin labeled phenylene-ethynylene foldamer. K. Matsuda, M. T. Stone, J. S. Moore

214. Synthesis of a fluorine-containing poly(aryl ether nitrile). D. Wang, B. Liu, Z. Gao, W. Hu, Z. Jiang, Z. Wu

215. Synthesis of a novel linear oligomer for PEDEK. J. Cao, H. Na, C. Zhang, X. Li, Z. Wu

216. Synthesis of a photoresponsive and thermosensitive azo polyelectrolyte and its thermo-controllable self-assembly process. X. Liu, X. Wang, D. Liu

217. Synthesis of Amphiphilic Poly(phenylacetylenes) Bearing Protected Nucleoside Pendents. J. Chen, K. K. L. Cheuk, Z. Xie, J. W. Y. Lam, B. Z. Tang

218. Synthesis of an optically active ephedrine-bearing poly(phenyleneethynylene) for asymmetric catalysis. C. Sun, Q. Hu

219. Synthesis of conjugated polymer precursors by living ring-opening metathesis polymerization. H. S. Bazzi, H. F. Sleiman

220. Synthesis of cyclic polydimethylsiloxane by coupling of disilanol-terminated linear siloxanes. H. W. Beckham, B. M. White, W. P. Watson, E. E. Barthelme

Section C

Unknown Site
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Self-assembled Photonic Band Gap Materials


E. L. Thomas and N. Balsara, Organizer

6:00 - 8:00

221. H-aggregation and micelles of a photoresponsive polyelectrolyte with branched azo side chains. Y. Deng, X. Tuo, H. Cheng, X. Wang

222. High yield precursor polymer for inverse carbon opal photonic materials. M. W. Perpall, K. P. U. Perera, D. W. Smith Jr., S. H. Foulger, J. Ballato, J. DiMaio

223. Hydrogen-bonded side-chain liquid crystalline block copolymers for photonic bandgap materials. C. Chao, C. K. Ober, C. Osuji, E. L. Thomas

224. Infiltration of 3D photonic crystals with embedded structures. S. A. Pruzinsky, W. Lee, Y. Lee, P. V. Braun

225. Two-dimensional patterning of colloidal arrays on polymer templates for photonic applications. H. Zheng, I. Lee, M. F. Rubner, P. T. Hammond

226. Water soluble Cationic Poly(p-phenylene vinylene) (PPV). X. Chen, F. Wudl

MONDAY MORNING

Section A

Unknown Site
Unknown Room

General Papers

Polymer Synthesis I


D. Garcia, Organizer
T. E. Long, Presiding

8:00 – 227. Synthesis and Characterization of Telechelic Multiple Hydrogen Bonded (MHB) Macromolecules via Living Anionic Polymerization. K. Yamauchi, T. E. Long

8:20 – 228. Synthesis, characterization and morphologial influence of bisphenol structure on the direct synthesis of sulfonated poly(arylene ether sulfone) copolymers W. L. Harrison, F. Wang, Y. Kim, M. Hickner, J. E. McGrath

8:40 – 229. Candida antarctica Lipase-B Catalyzed Regioselective Modification on Dendrimers from bis-MPA. A. Kumar, B. Kalra, R. Kumar, V. Parmar, J. L. Hendrick, R. A. Gross

9:00 – 230. Chiral polyesters by in-vitro enzymatic catalysis. K. S. Bisht, T. F. Al-Azemi, L. Kondaveti

9:20 – 231. Enzymatic surface-initiated polymerization of 3-(R)-hydroxybutyryl-CoA: Surface modification of a solid substrate with a biodegradable and biocompatible polymer. Y. Kim, H. Paik, C. K. Ober, G. W. Coates, C. A. Batt

9:40 – 232. Enzymatic Synthesis of Functionalized Polyphenolics for Optical Applications. V. Kumar, V. S. Parmar, L. Samuelson, J. Kumar, A. L. Cholli

10:00 – 233. Lipase catalyzed model transacylation reactions of aliphatic polyesters. A. Mahapatro, B. Kalra, A. Kumar, R. Gross

10:20 – 234. Macromolecular crowding accelerates DNA cleavage reaction catalyzed by DNA nucleases. J. J. Li, W. Tan

10:40 – 235. Microbial production of a self-assembling amphiphilic protein polymer. N. L. Goeden, J. D. Keasling, S. J. Muller

11:00 – 236. Poly(N-isopropylacrylamide) core-shell microgels: Synthetic fundamentals and characterization. C. D. Jones, L. A. Lyon

11:20 – 237. Free radical copolymerization of maleic anhydride and norbornene in the presence of a Lewis acid catalyst. A. J. Pasquale, T. E. Long

11:40 – 238. Preparation of nucleoside methacrylates, PEG-poly(nucleoside) diblocks, and their formation of supramolecular assemblies B. Kalra, A. Kumar, W. Gao, T. Glauser, M. Ranger, J. Hedrick, C. J. Hawker, R. A. Gross

Section B

Unknown Site
Unknown Room

General Papers

Polymer Synthesis II


D. Garcia, Organizer
T. Emrick, Presiding

8:00 – 239. Controlled polymerizations of functionalized 1,3-butadienes L. A. Rusch-Salazar, M. K. Rath-Murphy, V. V. Sheares

8:20 – 240. Templates for nanoporosity in low dielectric films: Preparation of pore generating macromolecules by ruthenium ring opening metathesis polymerization. E. F. Connor, M. C. Lares, J. L. Hedrick, R. D. Miller

8:40 – 241. Frontal polymerization synthesis of isopropylacrylamide hydrogels. R. P. Washington, O. Steinbock

9:00 – 242. Functional polymers through ROMP of cyclobutene derivatives. R. Charvet, B. M. Novak

9:20 – 243. Modifying photocrosslinked networks with living free radical initiators. J. B. Hutchison, C. J. Hawker, K. S. Anseth

9:40 – 244. Silicone magnetic fluids using poly(dimethylsiloxane)-b-poly(2-ethyl-2-oxazoline) as a steric stabilizer. K. S. Wilson, M. Rutnakornpituk, L. A. Harris, J. S. Riffle

10:00 – 245. a,a'- and b,b'-diperfluorohexyl substituted thiophene oligomers. Effect of perfluoroalkyl versus alkyl substitution on the thiophene oligomer core properties A. Facchetti, T. J. Marks

10:20 – 246. Alternating copolymerization of polar and nonpolar olefins by ring-opening metathesis polymerization. E. B. Coughlin, M. F. Ilker

10:40 – 247. CdSe-polymer composites prepared by surface initiated ring-opening metathesis polymerization. H. Skaff, F. Ilker, E. B. Coughlin, T. Emrick

11:00 – 248. Copolymerization of dimethacrylate-styrene (vinyl ester) networks. A. C. Rosario, E. Burts, B. Starr, J. S. Riffle

11:20 – 249. Electrocatalytic polymerization of polypyrrole on Al 2024-T3 alloy. C. Vang, M. Dewald, A. Richter, D. E. Tallman, G. G. Wallace, G. P. Bierwagen

11:40 – 250. Emulsion templating using high internal phase supercritical fluid emulsions. R. Butler, C. M. Davies, A. I. Cooper

Section C

Unknown Site
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Self-assembled Photonic Band Gap Materials

II


E. L. Thomas, Organizer
N. P. Balsara, Organizer, Presiding
M. R. T. Bockstaller, Presiding

9:00 – 251. Dielectrophoretic assembly of switchable two-dimensional photonic crystals with specific orientation. E. W. Kaler, S. O. Lumsdon, J. P. Williams, O. D. Velev

9:40 – 252. Colloidal Self-Assembly and Photonic Crystals. P. Wiltzius

10:20 – 253. Responsive microgel photonic crystals. L. A. Lyon, S. B. Kong, S. Eustis, J. D. Debord

10:40 – Intermission.

11:00 – 254. Pattern definition in self-assembled photonic crystals. P. V. Braun

11:40 – 255. Surface Relief Grating Induced Three Dimensional Colloidal Crystal Structures. D. Kim, D. K. Yi, E. Seo

Multi-Layered Polyelectrolyte-Based Materials: Synthesis, Characterization and Applications

Patterning

Cosponsored with Division of Colloid and Surface Chemistry
See Page X

MONDAY AFTERNOON

Section A

Unknown Site
Unknown Room

2002 ACS Polymer Division P.J. Flory Award in Polymer Education Honoring Ulrich Suter


P. Smith, Organizer, Presiding

1:00 – Introductory Remarks.

1:05 – 256. Role of commercial software in polymer education. B. E. Eichinger

1:40 – 257. Reflections on graduate polymer education. D. N. Theodorou

2:15 – 258. Entanglement effects revisited. K. Kremer, R. Everaers

2:50 – Intermission.

3:15 – 259. Product design for polymers: Case studies in undergraduate chemical engineering education. G. C. Rutledge

3:50 – 260. Educational benefits from high level programming languages in materials. M. Utz

4:25 – 261. Potential of modeling in polymer education. U. W. Suter

5:00 – Reception, ETH Zurich

Section B

Unknown Site
Unknown Room

Recent Advances in Polymer Synthesis:Review and Progress in Methodology and Self-Assembly


C. J. Hawker, Organizer, Presiding

1:00 – 262. Self-assembly of dendron rodcoil molecules into nanoribbons. S. I. Stupp, E. Zubarev, J. Hartgerink, E. Beniash, L. Li

1:30 – 263. Self-assembly and polymerization at various interfaces. D. T. McQuade, H. M. Jung

2:00 – 264. Supramolecular polymers in action. A. W. Bosman, B. J. B. Folmer, J. H. K. K. Hirschberg, H. M. Keizer, R. P. Sijbesma, E. W. Meijer

2:30 – 265. Synthetic methodologies for the surface derivatization of shell crosslinked nanoparticles. M. L. Becker, M. J. Joralemon, J. Liu, Q. Ma, K. Shanmugananda Murthy, K. Qi, E. E. Remsen, Q. Zhang, K. L. Wooley

3:00 – 266. Core-shell polymeric nanoparticles by self-assembly and step-growth polymerization. D. M. Knauss, S. L. Clark

3:30 – 267. New polyolefin elastomers: Advances based on catalyst discovery. G. W. Coates, L. R. Rieth, P. D. Hustad

4:00 – 268. Nanostructured macromolecular systems from block copolymers. R. B. Grubbs, J. M. Dean, F. S. Bates, L. B. Sessions, R. N. Lau, J. T. McCann

4:30 – 269. Dendritic polymers as multifunctional supports and nanocarriers for drugs. R. Haag, M. Krämer, J. F. Stumbé, S. Krause, A. Komp, S. Prokhorova

Section C

Unknown Site
Unknown Room

Self-assembled Photonic Band Gap Materials

III


E. L. Thomas and N. P. Balsara, Organizer
P. V. Braun and T. J. Bunning, Presiding

1:00 – 270. Superparamagnetic colloidal particles for magnetically controllable photonic crystals. S. A. Asher, X. Xu, G. Friedman, K. D. Humfeld

1:40 – 271. Holographic formation of switchable liquid crystal-based photonic crystals. T. J. Bunning, L. V. Natarajan, V. P. Tondiglia, S. Chandra, R. L. Sutherland, D. W. Tomlin

2:20 – 272. Multi-photon polymerization of waveguide structures within 3D photonic crystals. W. Lee, S. A. Pruzinsky, P. V. Braun

2:40 – Intermission.

3:00 – 273. Template-Directed Self-Assembly of Spherical Colloids and Its Applications. Y. Xia

3:40 – 274. Three dimensionally ordered poly(ferrocenylsilane) and magnetic ceramic inverse opals by colloidal crystal templating. A. C. Arsenault

4:00 – 275. Polyelectrolyte multilayer-based photonic bandgap structures. T. C. Wang, R. E. Cohen, M. F. Rubner

4:20 – 276. 2D Functional Colloidal Arrays on Surfaces for Photonic Wave Guides Using Polyelectrolyte Multilayers as Templates. I. Lee, H. Zheng, M. F. Rubner, P. T. Hammond

4:40 – 277. Fabrication and surface plasmon resonance (SPR) properties of polystyrene micro-sphere thin film arrays. K. Shinbo, S. Miyabayashi, H. Kobayashi, F. Kaneko, K. Kato, M. Tanaka, R. C. Advincula

Multi-Layered Polyelectrolyte-Based Materials: Synthesis, Characterization and Applications

Permeability

Cosponsored with Division of Colloid and Surface Chemistry
See Page X

MONDAY EVENING

Multi-Layered Polyelectrolyte-Based Materials: Synthesis, Characterization and Applications

Poster Session

Cosponsored with Division of Colloid and Surface Chemistry
See Page X

TUESDAY MORNING

Section A

Unknown Site
Unknown Room

2002 ACS Award in Applied Polymer Science Honoring James E. McGrath

I


T. E. Long, L. M. Robeson, and D. R. Paul, Organizer
C. D. Smith, Presiding

8:30 – 278. Electrostatic Processing of Polymers. G. E. Wnek

9:00 – 279. Surface science and wetting dynamics of hydrosilation- and alkoxysilane-cured polydimethylsiloxane and relevance to silicone biomedical applications. K. J. Wynne

9:30 – 280. Novel implantable semipermeable biomembranes. J. P. Kennedy

10:00 – Intermission.

10:15 – 281. New polymers for nanolithography in the 21st century: How chemists respond to Moore's law. R. D. Allen, R. Sooriyakumaran, H. Ito, G. M. Wallraff, H. D. Truong, C. E. Larson

10:45 – 282. Electroactive polymeric and organic materials for thin-film-transistor applications. A. J. Lovinger, Z. Bao, H. E. Katz

11:15 – 283. Polyimides From 2,3,3',4'-Biphenyltetracarboxylic Dianhydride and Aromatic Diamines P. M. Hergenrother, K. A. Watson, J. G. Smith Jr., J. W. Connell, R. Yokota

11:45 – 284. Aromatic poly(pyridinium salt)s: Photoreduction in amide solvents. F. Lin, F. W. Harris

Section B

Unknown Site
Unknown Room

Chromogenic Phenomena in Polymers: Tunable Optical Properties

Electrochromic Polymers and Devices


D. J. Kiserow, Organizer
S. A. Jenekhe, Organizer, Presiding

8:00 – Introductory Remarks.

8:10 – 285. Electrochromic devices based on polymer films. Electrochemical characterization and devices of benzimidazolebenzophenanthroline (BBL and BBB) and 3, 7-[bis (4-phenyl quinoline)] 10-methyl phenothiazine (PPTZPQ) polymers A. J. Bard, J. Choi, S. Ozer, F. Fungo, S. A. Jenekhe

8:40 – 286. Electrochromic devices from layer-by-layer thin films. D. M. DeLongchamp, P. T. Hammond

9:00 – 287. Conducting Polymer based dynamic IR-electrochromics for spacecraft thermal control. P. Chandrasekhar, B. J. Zay, D. Ross, T. McQueeney, G. C. Birur, T. Swanson, L. Kauder, D. Douglas

9:30 – 288. Near infrared electrochromic polymers for variable optical attenuation. Z. Y. Wang, Y. Qi, P. Desjardins, F. Wu

10:00 – 289. Optical tuning of conjugated polymers via post-functionalization. S. Holdcroft, Y. Li, G. Vamvounis

10:30 – 290. Tuning organizational structures and materials properties of linear and hyperbranched polymers by internal perturbations and external stimuli. B. Z. Tang

11:00 – 291. Substituent Effects upon Protonation-Induced Red Shift of Phenyl-Pyridine Copolymers. S. Scheiner, T. Kar

11:30 – 292. Electroluminescence and electrochromism within and beyond the visible range. J. R. Reynolds, M. Bouguettaya, B. S. Harrison, J. Hwang, T. J. Foley, I. Schwendeman, J. Shim, P. H. Holloway, J. M. Boncella, K. S. Schanze, D. B. Tanner, S. Ramakrishnan, G. Padmanaban

Section C

Unknown Site
Unknown Room

Polymer Diffraction Methods

Methods


K. H. Gardner, Organizer
J. Blackwell, Organizer, Presiding

8:40 – Introductory Remarks.

8:45 – 293. Structural studies of biological & synthetic polymers using x-ray and neutron diffraction. V. T. Forsyth, I. Parrot, K. H. Gardner, P. Lagan

9:15 – 294. Neutron and synchrotron X-ray fiber diffraction studies of cellulose polymorphs. Y. Nishiyama, H. Chanzy, P. Langan

9:45 – 295. Time-resolved X-ray diffraction of biaxial deformation of polymer materials. W. Fuller, A. Mahendrasingam, A. K. Wright, C. Martin, D. J. Blundell

10:15 – Break.

10:30 – 296. Understanding the broad Q scattering from miscible polymer blends. G. R. Mitchell, T. Gkourmpis

11:00 – 297. Neutron structure analyses and structual disorders of poly(p-phenylenebenzobisoxazole) and poly(p-phenylenebenzobisthiazole). Y. Takahashi

11:30 – 298. Crystalline order in polydiethylphosphazene: New applications of the Rietveld method. S. V. Meille, A. Farina, S. Brückner

Multi-Layered Polyelectrolyte-Based Materials: Synthesis, Characterization and Applications

Semiconductors

Cosponsored with Division of Colloid and Surface Chemistry
See Page X

TUESDAY AFTERNOON

Section A

Unknown Site
Unknown Room

2002 ACS Award in Applied Polymer Science Honoring James E. McGrath

II


T. E. Long and L. M. Robeson, Organizer
D. R. Paul, Organizer, Presiding

1:30 – 299. Systematic series of ‘model’ PTMO based segmented polyurethanes revisited: Insights using atomic force microscopy. A. Aneja, G. L. Wilkes

2:00 – 300. Organic Catalyst: A New and Broadly Useful Strategy for Living Polymerization. J. L. Hedrick, E. F. Connor, G. Nyce, A. Moeck

2:30 – 301. Interactions and reactions at the polymer chain end: From Davidson 120A to Hahn 3009. T. E. Long, J. R. Lizotte, A. J. Pasquale, K. Yamauchi, D. T. Williamson, C. L. Hudelson, L. Kilian, Q. Lin

3:00 – Intermission.

3:15 – 302. CO2 Technology Platform. J. M. DeSimone

3:45 – Introductory Remarks.

3:55 – 303. Award Address (ACS Award in Applied Polymer Science, sponsored by ). From cellulose to proton exchange membranes: Forty-five years in the vineyards J. E. McGrath

Section B

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Chromogenic Phenomena in Polymers: Tunable Optical Properties

Photochromic and Stimuli Responsive Polymers


S. A. Jenekhe, Organizer
D. J. Kiserow, Organizer, Presiding

1:00 – 304. Synthesis, properties, and applications of photochromic amorphous molecular materials and electrochromic polymers Y. Shirota, H. Nakano, I. Imae, Y. Osedo, H. Utsumi, T. Ujike, T. Takahashi

1:30 – 305. Photoinduced chirality in thin films of achiral azobenzene liquid crystalline copolymers. A. Natansohn, Y. Wu, P. Rochon

2:00 – 306. Photochromic blends of aromatic poly(pyridinium salt)s. F. Lin, F. W. Harris

2:20 – 307. Investigation of the thermochromic properties of polythiophenes in host polymers. B. L. Lucht, W. B. Euler, O. J. Gregory

2:40 – 308. Chromic transitions and nano-mechanical properties of (poly)diacetylene molecular layers. R. W. Carpick, D. Y. Sasaki, A. R. Burns, M. A. Eriksson, M. S. Marcus

3:10 – 309. Chiroptical properties of amorphous azopolymer films induced by elliptically polarized light. M. Kim, D. Kim

3:30 – 310. Enzymatically synthesized electronic and photoactive macromolecular dyes. J. Kumar, W. Liu, S. Lee, S. Yang, S. Tripathy, L. A. Samuelson

4:00 – 311. Absorption, photoluminescence and energy migration in conducting polymers with multiple phases M. J. Winokur, W. Chunwaschirasiri, D. Sherlock, M. Sumstine, R. West

4:30 – 312. Luminescent polymer coatings for pressure, temperature and mechanical strain imaging K. S. Schanze

Section C

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Polymer Diffraction Methods

Biopolymer Structure


J. Blackwell, Organizer
K. H. Gardner, Organizer, Presiding

1:30 – 313. Structural mechanism of self-assembly and polymorphic supercoiling of the bacterial flagellum. K. Namba

2:00 – 314. X-ray fiber diffraction analysis of amyloid assemblies. D. A. Kirschner, H. Inouye, J. P. Bond, S. P. Deverin, M. T. Teeter, O. M. A. El-Agnaf, C. Henry, C. E. Costello, A. Lim

2:30 – 315. Folding of a fibrous protein and its self-assembling peptides. A. Mitraki, A. Papanikolopoulou, V. T. Forsyth, V. Forge, J. Hernandez, R. Ruigrok

3:00 – Break.

3:15 – 316. Fiber diffraction on polysaccharides: A critical review of methods. P. Zugenmaier

3:45 – 317. Interactions of cations and water molecules with polysaccharide helices in oriented fibers and correlation with rheological properties. R. Chandrasekaran, S. Janaswamy, W. Bian

4:15 – 318. Implications of the crystal structure of NaI-cellobiose and a hybrid potential energy surface for cellulose structures. A. D. French, G. P. Johnson, Z. Peralta-Inga, E. D. Stevens, M. K. Dowd

Multi-Layered Polyelectrolyte-Based Materials: Synthesis, Characterization and Applications

Optics

Cosponsored with Division of Colloid and Surface Chemistry
See Page X

TUESDAY EVENING

Section A

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Chemistry and Engineering of Polyolefins

Cosponsored with Society of Plastics Engineers, and Division of Polymeric Materials: Science and Engineering
R. E. Campbell Jr. and J. Patton, Organizer

6:00 - 8:00

319. Dynamics of Long-Chain Branch Formation in Ethylene Polymerization with Constrained Geometry Metallocene Catalyst. M. Nele, J. B. P. Soares

320. Kinetic investigation of the living cationic polymerization of isobutylene with real-time monitoring using a mid-IR fiber optic probe. K. Kim, J. E. Puskas, S. Rohani

321. Melt grafting of glycidyl methacrylate onto POE/HDPE blend. F. Yang

322. New approach to measure copolymerization reactivity ratios by real time FTIR spectroscopy. S. Shaikh, S. Chattopadhyay, J. E. Puskas

323. Comprehensive kinetic model for the living carbocationic polymerization of Isobutylene. S. Shaikh, H. Peng, J. E. Puskas

324. Synthesis and characterization of functionalized polystyrenes. Y. A. Dahman, J. E. Puskas, M. Cunningham, Z. Merali

325. Theoretical studies of external donors' properties used in propylene polymerisation. C. Hansenne, D. Pattou, A. Standaert, G. Debras, L. Leherte, D. P. Vercauteren

326. Grafting of DiButyl Maleate and DiHexyl Maleate onto Atactic Polypropylene. N. Sharifi-Sanjani, M. Barari

327. Batch Emulsion Copolymerization of styrene with Dibutyl maleate and Dihexyl Maleate and characterization of copolymers. R. Faridi-Majidi, N. Sharifi-Sanjani

328. Recognition by Lipases of w-Hydroxyl Macroinitiators for Diblock Copolymer Synthesis. A. Kumar, Y. Wang, M. A. Hillmyer, R. A. Gross

329. Arborescent polyisobutylene-polystyrene block copolymers-a new class of thermoplastic elastomers. Y. Kwon, P. Antony, C. Paulo, J. E. Puskas

330. Pulse Speed Propagation in Polybutadiene (PBD) Networks. M. K. I. Hassan, J. E. Mark

331. Gel permeation chromatography and hyphenated techniques applied to the characterization of polyolefins. E. Meehan, S. O'Donohue, J. McConville

332. In-situ small-angle X-ray scattering study of crystallization in poly(ethylene/hexene) copolymer subjected to step shear. Z. Wang, H. Wang, B. S. Hsiao, D. Gersappe, C. C. Han

333. Morphological development in copolymer blends of poly(ethylene-co-hexene) and poly(ethylene-co-butene). K. Shimizu, H. Wang, Z. Wang, H. Kim, C. C. Han

334. Radiation induced cationic polymerization of epoxides. A time-resolved study of early steps and intermediates in polymerization of PGE and T123 in the presence of iodonium salt (CD1012) I. N. Ivanov, R. Dabestani

335. Surface Treatment Of Ultra-Fine ZnO and the Rheological Properties of PP/ZnO Composites. Y. Yan, Y. Zhao, G. You

336. Control of grafted polyolefins by ADMET and ATRP techniques. P. M. O'Donnell, K. B. Wagener

337. New developments concerning precisely placed short-chain branching in ethylene-co-alpha-olefin materials. K. B. Wagener, J. A. Smith, J. C. Sworen

338. Perfectly imperfect branching in polyethylene. J. C. Sworen, J. A. Smith, K. B. Wagener

339. Precisely placed gem-dimethyl branching in ADMET polyethylene. J. E. Schwendeman, K. B. Wagener

340. Chiral polyolefins bearing amino acids. K. B. Wagener, T. E. Hopkins, J. H. Pawlow, F. Tep

341. Amorphous telechelic hydrocarbon diols by ADMET. J. E. Schwendeman, K. B. Wagener, R. Sparer, M. E. Benz

342. Synthesis of the functional polypropylene and polystyrene. G. J. Jiang, R. Lin, H. Cheng

343. Rapid polymer characterization and on-line reaction monitoring. A. Tuchbreiter, A. Warmbold, R. Mülhaupt, B. Kappler, J. Honerkamp

Section B

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Chromogenic Phenomena in Polymers: Tunable Optical Properties


S. A. Jenekhe and D. J. Kiserow, Organizer
C. L. Fraser, Presiding

6:00 - 8:00

344. A thermally stable blue-emitting polyspirobifluorene. D. J. Park, Y. Y. Noh, J. Kim, D. Kim

345. Synthesis and characterization of a novel fluorene-based polyquinoline. S. Son, S. Jung, J. K. Kim, H. N. Cho

346. Exploratory synthesis and luminescent properties of novel p-conjugated tin-based alternating copolymers. H. K. Kim, N. S. Baek, B. Kim, E. Chae, J. Lee

347. Synthesis and electroluminescence studies of novel silicon-based copolymers containing oxadiazole units for polymeric light-emitting diodes. H. K. Kim, K. L. Paik, N. S. Baek, J. Lee

348. Conjugated polymer/lanthanide complex based blends as near-IR light emitting diodes. M. Bouguettaya, B. S. Harrison, T. J. Foley, J. Shim, P. H. Holloway, S. Ramakrishnan, J. M. Boncella, J. R. Reynolds, K. S. Schanze, G. Padmanaban

349. Tunable optical properties in polyfluorene copolymers by fluorine substitution. C. M. Chun, D. J. Park, Y. Y. Noh, J. Kim, D. Kim

350. Three-dimensional two-photon fluorescence lithographic imaging in a new photoresponsive polymer. K. D. Belfield, K. J. Schafer, S. J. Andrasik

351. Thin film solid-state electroluminescent devices based on tris(2,2'-bipyridine)ruthenium (II) complexes M. Buda, G. Kalyuzhny, A. J. Bard

352. Photophysics and photochemistry of platinum-acetylide complexes: models for metal-acetylide polymers. K. D. Glusac, K. S. Schanze

353. Synthesis and characterization of a novel jacketed polymers. S. Valiyaveettil, L. Shaowen

354. New electron-accepting p-conjugated polyquinoxalines with fluorene unit. S. Jung, D. H. Suh, H. N. Cho

355. Photochemical behaviour of carbosilane dendrimers of different generations with azobenzene terminal groups. A. Bobrovsky, A. Pakhomov, S. Ponomarenko, N. Boiko, V. Shibaev

356. Optical waveguides from trialkoxysilane-capped poly(methyl methacrylate)-titania materials. M. Wei, W. Chen

357. Electronic structure and bonding in metal porphyrins and phthalocyanines. S. Scheiner, M. Liao

358. C60-containing conjugated polymers and carbon nanotubes as optoelectronic nanomaterials. T. Lin, L. Dai, G. Wallace, A. Burrell, D. Officer

359. A precursor polymer approach towards the synthesis of polymethylsiloxane functionalized polypyrrole. P. Taranekar, R. Advincula

360. Synthesis and optical characterization of 1H-Pyrazole-based 6F-benzoxazole polymers incorporating a two-photon absorption chromophore. T. D. Dang, M. J. Matuszewski, M. J. Dalton, R. Kannan, J. E. Franklin, M. F. Durstock, L. -. Tan, F. E. Arnold

361. Synthesis and characterization of a two-photon absorbing and luminescent aminofluorenyl polymer. K. D. Belfield, A. R. M. Morales, V. M. Chapela, J. Percino

362. The precursor polymer approach to electrodeposition of high optical quality cross-linked polypyrrole ultrathin films. S. Deng, R. Advincula

Section C

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Polymer Diffraction Methods


K. H. Gardner and J. Blackwell, Organizer

6:00 - 8:00

363. Quantitative orientation measurement in multiple component polymer systems using WAXS. G. R. Mitchell, S. Saengsuwan, S. Bualek-Limcharoen

364. Probing the interaction of amphiphilic triblock copolymers with a biomimetic membrane. M. A. Firestone, S. Seifert

365. SANS from cyclic diblock copolymer solutions. R. Borsali, M. Schappacher, M. M. de Souza Lima, A. Deffieux, P. Lindner

366. Small angle neutrons and X-rays scattering from linear and star brush-like polymer solutions. M. Schappacher, M. M. de Souza Lima, R. Borsali, S. Lecommandoux, A. Deffieux, P. Lindner, C. Rochas, F. Chécot, D. Moinard

367. Structure evolution during ferroelectric phase transition in a vinylidene fluoride/trifluoroethylene copolymer. Z. Wang, E. Balizer, B. S. Hsiao, C. C. Han

368. Conformational Changes of Doped Polyaniline as Characterized by Small Angle Neutron Scaterring (SANS). A. R. Hopkins, R. A. Basheer, P. G. Rasmussen, B. K. Annis

369. Reorganization and recrystallization during melting of poly(trimethylene terephthalate). M. Dosiere, S. Hocquet

WEDNESDAY MORNING

Section A

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2002 ACS Award in Applied Polymer Science Honoring James E. McGrath

III


T. E. Long and D. R. Paul, Organizer
L. M. Robeson, Organizer, Presiding

8:30 – 370. Transport Processes in Polymer Electrolytes for Fuel Cells. T. A. Zawodzinski

9:00 – 371. Effect of organoclay structure on polymer nanocomposite formation and properties. D. R. Paul, T. D. Fornes, P. Yoon

9:30 – 372. Branched polymer architectures by living anionic polymerization. D. M. Knauss, H. A. Al-Muallem, T. Huang, J. T. Bender

10:00 – Intermission.

10:15 – 373. Nanostructured polymeric materials for microelectronics applications. K. R. Carter

10:45 – 374. Magnetic Nanostructured Fluids. J. S. Riffle, M. Rutnakornpituk, S. Lin-Gibson, J. P. Dailey, L. A. Harris

11:15 – 375. Fuel cell research at Virginia Tech: A student's perspective. M. A. Hickner

Section B

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Chromogenic Phenomena in Polymers: Tunable Optical Properties

Electroluminescence and Tunable Emission


S. A. Jenekhe and D. J. Kiserow, Organizer
B. Kippelen, Presiding

8:00 – 376. Excitation confinement in electroluminescent conducting polymers. A. J. Epstein, E. M. Kyllo, F. C. DeLucia Jr., D. K. Wang, T. L. Gustafson

8:30 – 377. New regioregular electroluminescent conjugated polymer for green light-emitting diodes. C. J. Tonzola, M. M. Alam, S. A. Jenekhe

8:50 – 378. Novel silicon-based alternating copolymers and their metal-chelated complexes: synthesis, photophysical properties, and LED applications H. K. Kim, N. S. Baek, K. L. Paik

9:20 – 379. Blue light emitting polymers and devices. Q. Pei, S. Pyo, S. Chang, Y. Yang

9:50 – 380. Semiconductor Nanocrystals: Single dots, charged dots, lasing dots M. G. Bawendi

10:20 – 381. Spirobifluorene-linked orthogonal polymers with controlled conjugation lengths. R. D. Miller, F. Doetz, A. R. Murphy, V. Y. Lee, J. C. Scott, L. Bozano, R. Smith, C. Bacilieri

10:50 – 382. Spiro-linked ter- and pentafluorenes for stable and efficient blue emission. D. Katsis, Y. Geng, J. J. Ou, S. W. Culligan, A. Trajkovska, S. H. Chen, L. J. Rothberg

11:10 – 383. Use of polybenzobisazoles as electron transport materials for light emitting diodes. M. M. Alam, S. A. Jenekhe

11:30 – 384. Polarized electroluminescence in double layer LEDs with perpendicularly oriented polymers. A. Bolognesi, C. Botta, D. Facchinetti, P. Strohriegl, K. Kreeger, M. Jandke, A. Relini, R. Rolandi, S. Blumstengel

12:00 – 385. Tuning the electroluminescence in polymer-based light emitting diodes. S. A. Carter

Section C

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Polymer Diffraction Methods

Structure Evolution


K. H. Gardner and J. Blackwell, Organizer
W. Fuller, Presiding

8:45 – 386. Teaching x-ray diffraction concepts with Flash® movies and VIs. I. R. Harrison

9:15 – 387. Transient structure formation during shear-induced crystallization of isotactic polypropylenes. J. A. Kornfield, D. W. Thurman, J. P. Oberhauser, L. Fernandez Ballester, M. Seki

9:45 – 388. Detection of precursors of crystallization in polymers as revealed by simultaneous SAXS and WAXS. F. J. Baltá-Calleja, F. Ania

10:15 – 389. Synchrotron studies of molecular reorganisation prior to strain-induced crystallization in polymers. A. Mahendrasingam, A. K. Wright, C. Martin, D. J. Blundell, W. Fuller

10:45 – Break.

11:00 – 390. Deformation of polymers in micron- and submicron sized X-ray beams. C. Riekel, M. Burghammer, M. C. Garcia, A. Gourrier, S. Roth

11:30 – 391. Use of X-ray diffraction and stretching calorimetry to follow structural transformations during deformation of polyethylene with low degrees of crystallinity. S. N. Chvalun, V. M. Neverov, Y. K. Godovsky, N. P. Bessonova, J. Blackwell

Section D

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Chemistry and Engineering of Polyolefins

Emerging Frontiers

Cosponsored with Society of Plastics Engineers, and Division of Polymeric Materials: Science and Engineering
J. Patton, Organizer
R. E. Campbell Jr., Organizer, Presiding

8:15 – Introductory Remarks.

8:20 – 392. Stereoblock PMMA and polypropylene-b-PMMA stereo-diblock copolymers by metallocene/ Lewis acid hybrid catalysts. E. Y. Chen, A. D. Bolig, J. Jin, J. Xu

9:00 – 393. Polyolefin block copolymers-designing microphase separated architectures for optical properties. S. Hahn, R. Cieslinski, J. Hahnfeld, M. A. Jones, C. Leibig, J. Milhaupt, G. Meyers, B. Landes, C. Langhoff, G. Parsons, M. Reinhardt, D. Yontz

9:40 – 394. Development of high-throughput techniques for olefin polymerization catalyst discovery. V. Murphy

10:20 – 395. Metallocene-mediated Olefin Polymerization with A Consecutive Chain Transfer Reaction to Stryenic Molecule and Hydrogen; Synthesis of Telechelic Polyolefins and Polyolefin Block Copolymers. T. C. Chung, J. Y. Dong

11:00 – 396. Catalyst-cocatalyst interactions and nuclearity effects in single-site olefin polymerization processes. T. J. Marks

Multi-Layered Polyelectrolyte-Based Materials: Synthesis, Characterization and Applications

Biomaterials

Cosponsored with Division of Colloid and Surface Chemistry
See Page X

WEDNESDAY AFTERNOON

Section A

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2002 ACS Award in Applied Polymer Science Honoring James E. McGrath

IV


T. E. Long, L. M. Robeson, and D. R. Paul, Organizer
J. S. Riffle, Presiding

1:00 – 397. Enhanced interfacial adhesion of carbon fiber to vinylester resin via plasma etching and plasma plymerization coating. H. Kang, N. Kim, T. Yoon

1:30 – 398. Fifteen years of rotaxanes and polyrotaxanes at Virginia Tech. H. W. Gibson

2:00 – 399. Recent advances in thermal step-growth cyclopolymerization of aromatic trifluorovinyl ethers and ortho-diynes. D. W. Smith Jr.

2:30 – Intermission.

2:45 – 400. Ultra Low-k Dielectric Materials for High Performance Interconnects. J. C. Hedrick, C. S. Tyberg, E. Huang, M. Sankarapandian, J. G. Ryan

3:15 – 401. Plasticization of acrylic copolymers with absorbed carbon dioxide. D. G. Baird, M. J. Bortner, J. E. McGrath

3:45 – 402. High molecular weight, high strength silicone-urea elastomers: Preparation and properties I. Yilgor, E. Yilgor

4:15 – 403. Development of coating resin technology. D. C. Webster

Section B

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Chromogenic Phenomena in Polymers: Tunable Optical Properties

Polymers for Chemical- and Bio-sensors


S. A. Jenekhe and D. J. Kiserow, Organizer
P. T. Hammond, Presiding

1:30 – 404. Self-assembled "polymers" on nanoparticles: superquenching and sensing applications. L. Lu, R. M. Jones, T. S. Bergstedt, D. McBranch, D. Whitten

2:00 – 405. Photophysics and quenching of a water-soluble poly(p-phenylene ethynylene) sulfonate. C. Tan, M. R. Pinto, K. S. Schanze

2:20 – 406. Polydiacetylenic lipid assemblies: "smart" materials for colorimetric biosensing and structural transformation in charge-induced chromatic transition. Q. Cheng, J. Song, R. C. Stevens

2:50 – 407. Fluorescent Electrospun Polymer Films For the Detection of Explosives. X. Wang, S. Lee, C. Drew, K. J. Senecal, J. Kumar, L. Samuelson

3:10 – 408. Site-isolated luminescent lanthanide complexes with biocompatible polymeric ligands. C. L. Fraser, J. L. Bender, P. S. Corbin, D. H. Metcalf, F. S. Richardson, E. L. Thomas, A. Urbas

3:40 – 409. DNA-chromic cationic polythiophene derivative. M. Leclerc, H. A. Ho

4:10 – 410. Quinoline-containing poly(aryleneethynylene)s. U. H. F. Bunz, C. G. Bangcuyo

4:40 – 411. Tunable photoluminescence of poly(quinoline)s in silica. Y. Okamoto, S. W. Ho, W. Y. Huang, T. K. Kwei

5:10 – 412. Synthesis, photophysical characterization and thin film self-assembly of a PPE-type conjugated polyelectrolyte M. R. Pinto, J. R. Reynolds, K. S. Schanze

Section C

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Polymer Diffraction Methods

Polymer Blends


K. H. Gardner and J. Blackwell, Organizer
B. L. Farmer, Presiding

1:30 – 413. Crystallisation in block copolymers: Confinement versus breakout. A. J. Ryan, J. Xu, J. P. A. Fairclough, S. Mai

2:00 – 414. Nano-tailored polymer crystallization in the HPL phase of a PS-b-PEO diblock copolymer. L. Zhu, S. Z. D. Cheng, Y. Chen, P. Huang, Q. Ge, R. P. Quirk, B. S. Hsiao, F. Yeh, L. Liu

2:30 – 415. Chain folding in block copolymers crystallised from solution. J. Xu, A. J. Ryan, J. P. A. Fairclough, S. Mai

3:00 – Break.

3:30 – 416. Small angle neutron scattering of diblock copolymer PS-PBLG: Rod-coil to coil-coil transition. J. da Siva Crespo, S. Lecommandoux, R. Borsali, H. -. Klok, V. Soldi

4:00 – 417. Dislocation-controlled hexagonally perforated layer phase in a PEO-b-PS diblock copolymer. L. Zhu, P. Huang, Y. Chen, S. Z. D. Cheng, Q. Ge, R. P. Quirk, B. S. Hsiao, F. Yeh, L. Liu

4:30 – 418. Lower critical ordering transition of a triblock copolymer melt. Y. K. Kwon, J. S. Kim, K. H. Lee, G. Kim

Section D

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Chemistry and Engineering of Polyolefins

Ethylene/alpha-Olefin Copolymers

Cosponsored with Division of Polymeric Materials: Science and Engineering
R. E. Campbell Jr., Organizer
J. Patton, Organizer, Presiding

1:30 – 419. Recent advances in zirconocene catalyzed ethylene-styrene copolymerization and olefin (co)polymerization. T. Arai, S. Hanasato, M. Nakajima, T. Ohtsu

2:10 – 420. Pyridyl-Imine derived olefin polymerization catalysts. R. E. Murray, V. M. George, D. L. Nowlin, C. C. Schultz, J. L. Petersen

2:40 – 421. Synthesis of new late transition metal catalysts containing nitrogen-phosphine ligands for olefin polymerization. Z. Guan

3:20 – 422. Characterization of Branching in Low Density Polyethylene, High Density Polyethylene and Polyethylenes from Chain-Walking Catalysts P. M. Cotts

4:00 – 423. Structure and properties of blown film from blends of polyethylene and high melt strength polypropylene. A. C. Chang, L. Tau, S. P. Chum, A. Hiltner, E. Baer

Multi-Layered Polyelectrolyte-Based Materials: Synthesis, Characterization and Applications

Model Systems

Cosponsored with Division of Colloid and Surface Chemistry
See Page X

THURSDAY MORNING

Section A

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Chromogenic Phenomena in Polymers: Tunable Optical Properties

Tunable Reflection and Optically Switchable Materials


S. A. Jenekhe and D. J. Kiserow, Organizer
S. H. Chen, Presiding

8:00 – 424. Electrically switchable mirrors and optical components made from liquid crystal gels. R. A. M. Hikmet

8:30 – 425. Light-controllable multifunctional chiral photochromic liquid crystal copolymers for optical data recording and storage. V. P. Shibaev, A. Y. Bobrovsky, N. I. Boiko

9:00 – 426. Photoresponsive glassy liquid crystals for tunable reflective coloration. S. H. Chen, S. W. Culligan, H. P. Chen, Y. Geng, D. Katsis

9:30 – 427. Novel two-photon absorbing conjugated oligmers/polymers: Property modulation by p-center. Z. Huang, W. B. Heuer, C. S. P. Sung, O. Kim

10:00 – 428. Photochemical control of reflection colors of glass-forming non-polymeric cholesterics with azobenzene chromophore. N. Tamaoki, M. Moriyama

10:30 – 429. Optically switchable liquid crystals containing azobenzene chromophores. T. Ikeda, A. Shishido, O. Tsutsumi, A. Kanazawa

11:00 – 430. Chromogenic polymer gels with a constant volume. A. Seeboth, J. Kriwanek, D. Lötzsch

11:30 – 431. Hierachical morphology periodic domain walls in smectic-like rod-coil diblock copolymers. J. Park, E. L. Thomas

11:50 – 432. Self-assembly and liquid crystalline behavior of novel terphenylene derivatives. S. Valiyaveettil, S. B. M. Abubakar

Section B

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Polymer Diffraction Methods

Structure Determination I


K. H. Gardner and J. Blackwell, Organizer
P. Langan, Presiding

8:45 – 433. Structure of poly(ester amide)s derived from a-amino acids and related polyesters. J. Puiggalí, A. Almontassir, L. Franco, M. T. Casas

9:15 – 434. Structure of a cyanobiphenyl side chain liquid crystalline poly(silylenemethylene). S. Park, T. Zhang, L. V. Interrante, B. L. Farmer

9:45 – 435. A survey of x-ray fiber diffraction on crystalline structures of polyhydroxyalkanoates. R. H. Marchessault, J. Kawada, S. Raymond

10:15 – Break.

10:30 – 436. Helical hand in achiral and chiral polymers: a tool to analyze local processes in polymer crystallization. B. A. Lotz

11:00 – 437. Electron microscopy and diffraction of pentacene thin films. L. F. Drummy, P. K. Miska, D. C. Martin

11:30 – 438. Diffraction and modeling studies of chain conformation and packing in poly(di-n-alkylsilanes). M. J. Winokur, W. Chunwachirasiri, R. West

Section C

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Chemistry and Engineering of Polyolefins

Polypropylene: Old Monomer-New Polymers

Cosponsored with Division of Polymeric Materials: Science and Engineering
R. E. Campbell Jr., Organizer
J. Patton, Organizer, Presiding

8:20 – 439. Counterion influence on the kinetics of initiation, propagation, and termination for polymerization of 1-hexene as catalyzed by [rac-(C2H4(1-indenyl)2Zr(Me)]+ cations C. R. Landis, Z. Liu, C. B. White

9:00 – 440. Methylene-bridged bis(2-indenyl) metallocene catalysts. L. Resconi

9:40 – 441. Counter-Ion effects on poly(propylene) microstructure prepared using ansa-metallocene catalysts. S. Collins, M. Mohammed, S. Xin, M. Nele, A. Al-Humydi

10:20 – 442. Ultrahigh Molecular Weight Polypropene Elastomers By High Activity „Dual-Side" Hafnocene Catalysts. B. Rieger, C. Troll, J. Preuschen

11:00 – 443. Orientation dynamics and crystallization of elastomeric polypropylenes. G. G. Fuller, W. Wiyatno, J. Pople, A. P. Gast, R. Waymouth

THURSDAY AFTERNOON

Section A

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Chromogenic Phenomena in Polymers: Tunable Optical Properties

Imaging, Storage, Patterning, and New Polymers


S. A. Jenekhe and D. J. Kiserow, Organizer
S. Holdcroft, Presiding

1:30 – 444. Polymers for holographic imaging and displays. B. Kippelen, B. Domercq, J. A. Herlocker, R. D. Hrera, J. N. Haddock, C. Fuentes-Hernandez, G. Ramos-Ortiz, P. A. Blanche, N. Peyghambarian, A. Schulzgen, Y. Zhang, S. R. Marder

2:00 – 445. Toward plastic electronics: patterned electroactive organic materials using polymer-on-polymer stamping. P. T. Hammond

2:30 – 446. Tuning Optical Properties at the Molecular and Supramolecular Level. M. Rubner

3:00 – 447. Modulation of optical properties in new photosensitive polymers: 3-D optical data storage media. K. D. Belfield, K. J. Schafer

3:20 – 448. Quantum amplified isomerization: Photoinitiated electron transfer chain reactions in dewarbenzene substituted polymers. D. R. Robello, S. Farid, J. P. Dinnocenzo, J. G. Gillmore

3:40 – 449. Intermolecular electron-transfer across the encapsulation of helical amylose. J. Je, O. Kim

4:00 – 450. Hyperbranched oligomers and dendrimers of thiophene. C. Xia, X. Fan, R. Advincula

4:20 – 451. Polymer-titania optical thin films for optical waveguides. W. Chen, L. Lee

4:50 – 452. Electrodeposition and cross-linking of carbazole substituted polyacetylenes: Mixed band-gap conjugated ultrathin films. K. Onishi, R. Advincula, T. Nakai, S. M. A. Karim, T. Masuda

Section B

Unknown Site
Unknown Room

Polymer Diffraction Methods

Structure Determination II


K. H. Gardner and J. Blackwell, Organizer
S. Z. D. Cheng, Presiding

1:30 – 453. Lamellar morphology of poly(e-caprolactone) fractions. M. Dosiere

2:00 – 454. X-ray diffraction and optical ellipsometry: complementary techniques for the study of polymer structure. P. Cebe, P. Dai, G. Georgiev, B. Feinberg, N. Gilfoy, M. Capel

2:30 – 455. A Novel Diffraction Analysis for Estimate of Mesophase in Crystalline Polymer Fibers. S. Ran, B. S. Hsiao, B. Chu

3:00 – Break.

3:15 – 456. Diffraction information from low concentrated components in multicomponent polymer systems. A. Nogales, G. R. Mitchell, B. Pukanszky, B. Turcsanyi

3:45 – 457. Structural studies on naphthalene based rigid-rod benzobisthiazole polymers. S. Park, J. Lee, N. Venkatasubramanian, T. D. Dang, F. E. Arnold, B. L. Farmer

4:15 – 458. Structure formation in PBO fibers and the SAXS four-point pattern. C. Burger, S. Ran, D. Fang, D. Cookson, Y. Teramoto, P. M. Cunniff, P. J. Viccaro, B. S. Hsiao, B. Chu

Section C

Unknown Site
Unknown Room

Chemistry and Engineering of Polyolefins

Materials Science and Engineering

Cosponsored with Division of Polymeric Materials: Science and Engineering
J. Patton, Organizer
R. E. Campbell Jr., Organizer, Presiding

1:10 – 459. Polypropylene blend miscibility: Measurement and application. D. J. Lohse

1:50 – 460. Miscibility of polyolefins. W. W. Graessley

2:30 – 461. Modeling the synthesis of thermoplastic elastomers through olefin macromers generated in and ex situ. J. B. P. Soares, M. Nele

3:10 – 462. Shear-mediated crystallization of isotactic polypropylene: The role of long chain-long chain overlap. D. W. Thurman, M. Seki, J. P. Oberhauser, J. A. Kornfield

3:50 – 463. Probing miscibility, local dynamics, and chain packing in amorphous polyolefin blends by solid-state NMR J. L. White, X. Wang

4:30 – 464. Crystallization rates and molecular microstructure of fractions from Metallocene and Ziegler type Isotactic Poly(propylenes). R. G. Alamo, J. A. Blanco, E. J. Ritchson, P. K. Agarwal



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