FLUOROPOLYMER 2002

Current Frontiers and Future Trends

Savannah Marriott Riverfront
Savannah, Georgia
October 13-16, 2002

Sponsored by
The Division of Polymer Chemistry
American Chemical Society


 


Invitation & General Information

Although fluoropolymers are nearly 60 years old, they maintain a growth rate above the US GNP. In addition to perfluoropolymers, partially fluorinated polymers will continue to impact a wide range of technologies as better control of their unique optical, electronic, processing, extreme environment stability, and surface properties are achieved. This will be the second biannual FLUOROPOLYMER workshop sponsored by the Division of Polymer Chemistry. FLUOROPOLYMER 2000 was a tremendous success with a sell-out attendance. FLUOROPOLYMER 2002 will cover topics including synthesis, processing, properties, and applications of new as well as traditional fluoropolymers with special emphasis on "break-through" technologies and future commercial trends. To review the content of last Workshop see: "FLUOROPOLYMER 2000: Current Frontiers and Future Trends", D.W. Smith, Jr., Ed., EPS Division of eMedix, Hattiesburg, MS, 2001. Or visit: www.emedix.org

SESSION TOPICS INCLUDE:

  • TUTORIALS: organofluorine chemistry, fluoropolymer structure/property relationships, and "state of the fluoropolymer industry" and environmental impact trends.
  • Coatings and Surfaces
  • Optical and Electronic Applications
  • Membrane and Energy Applications
  • Semifluorinated Polymers
  • New Materials, Applications & Processes

    ORGANIZING TEAM:

  • Prof. Dennis Smith, Clemson University
  • Dr. Andrew Feiring, DuPont
  • Prof. Darryl DesMarteau, Clemson University
  • Dr. Bill Cogio, 3M / Dyneon
  • Prof. Ken Wynne, Virginia Commonwealth University
  • Dr. John Connell, NASA Langley
  • Prof. Patrick Cassidy, Southwest Texas State University

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    Accommodations

    The Savannah Marriott Riverfront is located 20 minutes from the Savannah International Airport. Located on the Historic Riverfront connected to world-famous River Street which offers unique shops, taverns, and restaurants. Voted "Top hotel in Savannah" in 2000 by Creative Loafing.

    Hotel reservations should be made directly with the Marriott, 100 General McIntosh Boulevard Savannah, GA 31401, Phone: 1-912-233-7722, Fax: 1-912-233-3765, www: http://www.marriotthotels.com Please request the special rates for the polymer group.

    Additional information on Savannah can be found at: www.savannah-visit.com

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    Program

    Sunday, OCTOBER 13, 2002

    1:30 P.M. REGISTRATION BEGINS (registration desk remains open throughout meeting)

    2:45 P.M. Prof. Dennis Smith, Clemson University, OPENING REMARKS

    TUTORIALS 1 - 3

    3:00 P.M. Prof. Darryl D. DesMarteau, Clemson University, "Why Fluorine?"

    4:00 P.M. Dr. Bill Coggio, 3M, "Fluorocarbon Elastomers and Plastics: An Introductory Overview"

    5:00 P.M. Prof. Ken Wynne, Virginia Commonwealth University, "Fluoropolymer Surface Science"

    5:00 P.M. WELCOME RECEPTION

    7:00 P.M. DINNER ON YOUR OWN


    MONDAY, OCTOBER 14, 2002

    7:30 A.M. CONTINENTAL BREAKFAST

    Session I. Optical and Electronics Applications (Chair - Dr. Christian Dreyer)

    8:15 A.M. Prof. Chris Ober, Cornell University, "Fluoropolymers in Advanced Lithography"

    8:45 A.M. Dr. William Farnham, DuPont, "Design of Transparent Fluoropolymer Photoresists"

    9:15 A.M. Prof. Darryl D. DesMarteau, Clemson University, "Tetrafluoroethylene Copolymers for 157 nm Lithography"

    10:15 A.M. BREAK

    10:30 A.M. Prof. Alex Jen, University of Washington, "Nanoscale Tailoring of Fluorodendrimers and Fluoropolymers for Photonic and Optoelectronic Applications"

    11:00 A.M. Dr. Christian Dreyer, Fraunhofer Institute, "New Triazine Containing Fluoropolymers for Use in Integrated Optics"

    11:30 A.M. Prof. Andres Hult, Swedish Royal Institute of Technology, "Fluorinated Dendritic Polymers and Dendrimers for Optical Waveguide Applications"

    12:00 N LUNCH

    1:30 P.M. Prof. Dennis Smith, Clemson University, "Perfluorocyclobutyl (PFCB) Copolymers for Microphotonics"

    Session II. Synthesis and Structure / Property Relationships (Chair - Prof. Ken Wynne)

    2:00 P.M. Dr. Vincenzo Arcella, Fluoropolymer R&D, Ausimont, "Amorphous Perfluoropolymers for High Performance Applications"

    2:30 P.M. Prof. Steve Clarson,University of Cincinnati, "Synthesis and Properties of Fluorosilicone Fluids and Elastomers"

    3:00 P.M. BREAK

    3:15 P.M. Prof. Joseph Thrasher, University of Alabama, "Recent Advances in Perfluoropolyalkylether (PFPAE) Chemistry"

    3:45 P.M. Dr. Richard R. Thomas, OMNOVA Solutions, Inc., "The Synthesis, Characterization and Unusual Surface Activity of a Series of Novel Architecture, Water Dispersible Poly(Fluorooxetane)s"

    4:15 P.M. Mr. Paul Tuckner, Dyneon, "Fluorocarbon Elastomers in Compression. The Relationship between Polymer Response and Application Performance."

    4:45 P.M. Prof. Patrick Cassidy, Southwest Texas State University, "New Step-Growth Fluoropolymers"

    5:30 P.M. SOCIAL AND POSTER SESSION

    6:30 P.M. DINNER ON YOUR OWN


    Tuesday, October 15, 2002

    7:30 A.M. CONTINENTAL BREAKFAST

    TUTORIAL 4

    8:45 A.M. Dr. James Sullivan, 3M, "State of the Fluoropolymer Industry and Regulatory Issues"

    Session III. Films and Ionomers (Chair - Dr. William Farnham)

    9:45 A.M. Prof. Steve Creager, Clemson University, "Fluoropolymer Electroltyes for Electrochemical Energy Conversion Devices"

    10:15 A.M. Prof. Robert Moore, The University of Southern Mississippi,, "Poly(Vinylidene Fluoride)/Perfluorosulfonate Ionomer Blends."

    10:45 A.M. BREAK

    11:00 A.M. Prof. Dvora Perahia, Clemson University, "From a Molecule to a Stable Film: The Factors Affecting Stability of Per Fluorinated Ionomer Thin Films"

    11:30 A.M. Dr. Terrance Vargo, Integument Technologies, Inc., "Advanced Thin Film Fluoropolymers Part II- Latest Improvements in Paint Replacement Appliqué Technology"

    12:00 N Dr. David Londono, DuPont, "Morphology of a Perfluorosulfonate Ionomer via In-situ SAXS: Deformation and Swelling"

    12:30 P.M. LUNCH

    Session IV. High Performance Semifluorinated Polymers (Chair - Prof. Patrick Cassidy)

    1:30 P.M. Prof. Frank Harris, University of Akron, "Polyimides Containing Pendent Perfluoromethyl Groups: Synthesis and Properties"

    2:00 P.M. Dr. John Connell, NASA Langley Research Center, "High Performance Semi-Fluorinated Polyimides for Space Applications"

    2:30 P.M. Prof. Harry Allcock, Pennsylvania State University, "Fluorinated Organophosphazene Polymers: Past, Present, and Future"

    3:00 P.M. BREAK

    3:15 P.M. Mr. Drew Davidock, University of Minnesota, "Novel Fluorinated Block Copolymers by Selective Chemical Modification: A New Route to Exploring Phase Behavior"

    3:45 P.M. Ramin Amin-Sanayei, ATOFINA Chemical Inc., "Flame Retardant Fluoropolymer Foams"

    4:15 P.M. Prof. John Fitch, Southwest Texas State University, "New Fluorine Containing Polyethers"

    4:45 P.M. Prof. Joseph DeSimone, University of North Carolina and North Carolina State University, "Updates on the Carbon Dioxide Technology Platform as it Relates to Fluoropolymer Synthesis and Processing"

    5:30 P.M. SOCIAL AND POSTER SESSION

    6:30 P.M. DINNER ON YOUR OWN


    Wednesday, October 15, 2002

    7:30 A.M. CONTINENTAL BREAKFAST

    Session V. New Materials and Processes (Chair - Prof. Steve Clarson)

    8:15 A.M. Prof. Ken Wynne, Virginia Commonwealth University, "Supercritical CO2 Swelling Behavior of Poly(vinylidene fluoride) and Post-Plasticization DSC Characterization"

    8:45 A.M. Prof. Krishna Kumar, Tufts University, "Protein Engineering Using Fluorinated Amino Acids"

    9:15 A.M. Prof. Mark McHugh, Virginia Commonwealth University, "Supercritical Fluid Solubility of Poly-p-(carbooctalkoxyphenylene)s with Fluorinated Side Chains"

    9:45 A.M. Dr. Michael E. Wright, NAWCWD, "The Synthesis of Poly-p-(alkyl benzoates) and Poly-p-(fluoro-alkyl benzoates): Regio-regularity and Processability Control Through the Polymerization Catalyst"

    10:15 A.M. Dr. Willie Lau, Rohm and Haas, "Emulsion Polymerization using Cyclodextrin as Phase Transport Catalyst"

    10:45 A.M. Dr. Susanta Banerjee, Defense Research and Development of India, "Novel Semi Fluorinated Poly(Ether Imide)S Derived From 4-aminobenzoxy-2'-trifluoromethyl-4'(4"-aminoaminobenzyl)"

    11:15 A.M. CLOSING REMARKS


     

    PAPER SUBMISSION

    There will be five oral sessions (ca. 50 speakers) and two poster sessions (ca. 50 posters in total). To submit an oral paper, send a title and brief abstract (150 words) to Dennis Smith, Clemson University Department of Chemistry Clemson, SC 29634 Phone: 864-656-5020 Fax: 864-656-6613 email: dwsmith@clemson.edu. To submit a poster, send a title and brief abstract (150 words) to Chris M. Topping, email: ctoppin@clemson.edu.

    A book of abstracts for presentations and posters will be distributed at the symposium. Accepted papers will require a one to two page extended abstract or preprint which may include tables or figures and references. Title and brief abstracts are due by July 15, 2002. Extended abstracts or one page preprints are due by Septmenber 2, 2002. A 12-point Times font on 8 1/2 x 11 paper with single spacing is preferred. Papers accepted for poster and oral presentations are due in the Polymer Division Business Office no later than September 2, 2002. Accepted papers should be sent to Kathy Linkous, Division of Polymer Chemistry, Inc., Virginia Tech, 410 Davidson Hall, MC 0279, Blacksburg, VA 24061, Fax: 540-231-2588, e-mail: kathyl@vt.edu. Both a hard copy and an electronic file is appreciated.

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    Registration

    The registration fee is $700 for Members of the Division of Polymer Chemistry and $750 for Non-Members ($175 Student Members, $225 Student Non-Members). There is a $175 fee for a Non-Participating Guest that may accompany you. Written cancellation or registration after September 2, 2002, will cost an additional $50. Checks may be made payable to the Division of Polymer Chemistry. In addition to handout material, the fee includes meals, receptions and breaks.

    Better yet: use the on-line registration form on the POLY website to register for the meeting. Payment may be made by credit card or check (payable to Division of Polymer Chemistry). Due to the limited space of this meeting, we strongly encourage early registration. Registration fees are listed on the Registration Form. A $50.00 late fee will be imposed for registrations received after September 2, 2002.

    To register send the completed registration form with remittance to:

    Lesia Robertson, Division of Polymer Chemistry, Inc.
    Virginia Tech
    410 Davidson Hall, M.C. 0279
    Blacksburg, VA 24061
    Phone: 540-231-3052
    Fax: 540-231-2588
    E-mail: lesiar@vt.edu


    Registration Form

    Prof. Dr. Mr. Ms. Mrs. Miss

    Name

    Organization

    Mailing Address

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    Phone Fax

    $700 Member Registration

    $750 Non-Member Registration

    $175 Member Student Registration

    $225 Non-Member Student Registration

    $175 Accompanying Guest

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    $50 Late Fee

    Total Amount Due: $

    Payment by: Check Credit Card

    VISA, Master Card, or American Express Exp. Date

    Account #

    Signature

    *A late fee is charged if registration is received after September 2, 2002.



    PAPER SUBMISSIONS (TITLE AND ABSTRACT) SHOULD BE SUBMITTED ASAP. EXTENDED ABSTRACTS OR ONE PAGE PREPRINTS ARE DUE BY JULY 31.

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